Now showing 1 - 2 of 2
  • Publication
    Toughening mechanism of thermoplastic starch nano-biocomposite with the hybrid of nanocellulose/nanobentonite
    (Elsevier, 2023)
    Lai Di Sheng
    ;
    ; ;
    Mariatti Jaafar@Mustapha
    ;
    ;
    High flexibility and toughness are key criteria for an effective bioplastic packaging film. However, in most studies, the flexibility of thermoplastic starch (TPS) films is always neglected when targeting their tensile strength improvement. Low film flexibility has limited the development of TPS films in replacing the petrochemical-based plastic packaging films. In this communication, we report a method to produce thermoplastic corn starch (TPCS) films with excellent mechanical strength, high flexibility and high toughness through the hybridization of two natural nanofillers: nanobentonite and nanocellulose. The synergistic effect of the hybrid nanofillers can be observed through the arrangement of alternating nacre structures where the nanobentonite silicate layers are responsible for mechanical strength, while the nanocellulose promotes free volume in the TPCS matrix and triggers high film elongation at break. Structural, morphological, and thermomechanical analysis were conducted, and the detailed strengthening mechanism of the TPCS hybrid nano-biocomposite films was revealed.
      5  31
  • Publication
    Investigation on recycling and reprocessing ability of self-healing natural rubber based on ionic crosslink network
    (De Gruyter Brill, 2024) ;
    Raa Khimi Shuib
    ;
    ;
    Fairul Sharin Abd Razak
    ;
    Noor Faezah Mohd Sani
    ;
    Trans Dai Lam
    Natural rubber (NR) is a complex material that is often discarded due to its three-dimensional structure. Recycling of rubber is difficult due to its complex structure, and only 1.7 million tonnes of waste, such as tyres and gloves, are considered recyclable. This study aims to develop self-healing rubber, which allows a product to recover without affecting structural reliability. Commercial NR was ionically crosslinked with zinc thiolate, forming an ionic crosslink network between rubber chains and zinc thiolate ions. The ionic crosslinks allow the rearrangement of rubber molecular chains under external heat, providing self-healing capabilities. The highest ionic crosslink density was found in NR with 35 phr zinc thiolate. The self-healing NR can recover 90 % of its initial properties at room temperature for 10 min and can be reprocessed and recycled three times without compromising its properties. It also shows excellent weldability, making it a promising material for repairing existing rubber products in heavy engineering applications.