Rozyanty Rahman
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Preferred name
Rozyanty Rahman
Official Name
Rozyanty, Rahman
Alternative Name
Rozyanty, A. R.
Rozyanty, R.
Rahman, Rozyanty Abdul
Rozyanty, Rahman
Rahman, Rozyanty A.
Rahman, R. A.
Rahman, R.
Main Affiliation
Scopus Author ID
35300412500
Researcher ID
GEK-5202-2022

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Effect of halogen free-flame retardants on the mechanical and morphological properties of Kenaf/Polyurethane foam composites

2020 , Nur Suhaili Mohd Soberi , Rozyanty Rahman , Firuz Zainuddin , Hazim Mohamad Amini

Kenaf/polyurethane foam (PUF) was synthesized form PUF and kenaf core fiber with expandable graphite (EG) and aluminum hydroxide (ATH) at varying amounts. In the production of polymer foam composites, the processing methods determine the properties of the final products. In this work, the potential of high energy milled on EG has reduced the EG platelet size to improve its dispersion in PUF matrix. From the results obtained, PU/KF/6ATH/10EG shows the highest mechanical properties, i.e. modulus and compression strength, while PU/KF/2ATH/5EG shows the lowest mechanical properties. Scanning Electron Microscope (SEM) shows the effect of adding kenaf fiber, EG and ATH in PUF to the foam cell structure and size.

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The influence of MMA esterification on interfacial adhesion and mechanical properties of hybrid kenaf bast/glass fiber reinforced unsaturated polyester composites

2021 , Rozyanty Rahman , Syed Zhafer Firdaus Syed Putra , Shayfull Zamree Abd. Rahim , Irwana Nainggolan , Bartłomiej Jeż , Marcin Nabiałek , Luqman Musa , Andrei Victor Sandu , Petrica Vizureanu , Mohd. Mustafa Al Bakri Abdullah , Dariusz Kwiatkowski , Izabela Wnuk

The demand for natural fiber hybrid composites for various applications has increased, which is leading to more research being conducted on natural fiber hybrid composites due to their promising mechanical properties. However, the incompatibility of natural fiber with polymer matrix limits the performance of the natural fiber hybrid composite. In this research work, the mechanical properties and fiber-to-matrix interfacial adhesion were investigated. The efficiency of methyl methacrylate (MMA)-esterification treatments on composites’ final product performance was determined. The composite was prepared using the hand lay-up method with varying kenaf bast fiber (KBF) contents of 10, 15, 20, 25, 30, 35 (weight%) and hybridized with glass fiber (GF) at 5 and 10 (weight%). Unsaturated polyester (UPE) resin and methyl ethyl ketone peroxide (MEKP) were used as binders and catalysts, respectively. Scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR) were used to examine the effects of MMA-esterification treatment on tensile strength and morphology (tensile fracture and characterization of MMA-esterification treatment) of the composite fabricated. The tensile strength of MMA-treated reinforced UPE and hybrid composites are higher than that of untreated composites. As for MMA treatment, 90 min of treatment showed the highest weight percent gain (WPG) and tensile strength of KBF-reinforced UPE composites. It can be concluded that the esterification of MMA on the KBF can lead to better mechanical properties and adhesion between the KFB and the UPE matrix. This research provides a clear reference for developing hybrid natural fibers, thus contributing to the current field of knowledge related to GF composites, specifically in transportation diligences due to their properties of being lightweight, superior, and involving low production cost.

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Effect of Different Filler Loading on Flexural Properties and Water Absorption Behavior of Kenaf Core Fiber Reinforced Polypropylene Composite

2020-11-24 , Mustapa N.R. , Rozyanty Rahman , Mohd Hanif Mohd Pisal

In this investigation, kenaf core fiber (KCF) reinforced polypropylene (PP) composite was prepared via extrusion and compression moulding. The effect of different ratio of KCF filler with PP on flexural properties of composite had been investigated. PP and KCF filler were prepared with different filler loading of 5, 10, 15, 20 and 25 wt% using twin-screw extruder at temperature 180 °C and rotor speed of 70 rpm, followed by compression moulding at the same temperature. The flexural tests were conducted to evaluate the flexural properties of the composite. The results obtained showed that the incorporation of KCF in PP increased the flexural strength and flexural modulus of the composite. The water absorption behaviour of the composite was also investigated. It was found that water absorption of composites increased with increasing of fiber content.

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Warpage optimisation using recycled polycar-bonates (PC) on front panel housing

2021-03-02 , Tamizi N.A.M.A. , Shayfull Zamree Abd. Rahim , Abdellah A.E.H. , Mohd. Mustafa Al Bakri Abdullah , Nabiałek M. , Wysłocki J.J. , Jeż B. , Palutkiewicz P. , Rozyanty Rahman , Mohd. Nasir Mat Saad , Mohd Fathullah Ghazli@Ghazali

Many studies have been done using recycled waste materials to minimise environmental problems. It is a great opportunity to explore mechanical recycling and the use of recycled and virgin blend as a material to produce new products with minimum defects. In this study, appropriate processing parameters were considered to mould the front panel housing part using R0% (virgin), R30% (30% virgin: 70% recycled), R40% (40% virgin: 60% recycled) and R50% (50% virgin: 50% recycled) of Polycarbonate (PC). The manufacturing ability and quality during preliminary stage can be predicted through simulation analysis using Autodesk Moldflow Insight 2012 software. The recommended processing parameters and values of warpage in x and y directions can also be obtained using this software. No value of warpage was obtained from simulation studies for x direction on the front panel housing. Therefore, this study only focused on reducing the warpage in the y direction. Response Surface Methodology (RSM) and Genetic Algorithm (GA) optimisation methods were used to find the optimal processing parameters. As the results, the optimal ratio of recycled PC material was found to be R30%, followed by R40% and R50% materials using RSM and GA methods as compared to the average value of warpage on the moulded part using R0%. The most influential processing parameter that contributed to warpage defect was packing pressure for all materials used in this study.

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A review on the effect of extrusion parameter on 3D printing filament diameter

2023 , Krishna Kumar Nitiyah , Luqman Musa , Mohamad Syahmie Mohamad Rasidi , Khairel Rafezi Ahmad , Shayfull Zamree Abd. Rahim , Rozyanty Rahman , Ahmad Azrem Azmi

Over the years, the extrusion technique has captured the attention of polymer industries by meeting the demand for polymer processing and fabrication of final products. Extrusion is a continuous process, and it has a lot of potential in the increasing polymer sector, especially in the three-dimensional (3D) printing sector. 3D printing is popular because the feedstock filament form is accessible and produce able. The properties of the filament used influence the printed part qualities regardless of the FDM parameters. This study provides information on how extrusion parameters affect the diameter of extruded filaments. This study reviews previous studies on the effect of varied extrusion settings on filament diameter. The review will serve as a resource for researchers in the 3D printing sector to fabricate their filaments for 3D printing. Overall, this paper will provide solutions to overcome issues in obtaining optimal filament diameters for future research projects.

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A review on graft compatibilizer for thermoplastic elastomer blend

2021-11-12 , Nitiyah K.K. , Luqman Musa , Mohamad Syahmie Mohamad Rasidi , Shayfull Zamree Abd. Rahim , Rozyanty Rahman , Ahmad Azrem Azmi , Rennie A.

A biodegradable thermoplastic elastomer (TPE) blend is developed by blending poly (lactic acid) (PLA) and natural rubber (NR) or epoxidized natural rubber (ENR) and it is a sustainable substitution in recent years for synthetic polymers. PLA is high in mechanical strength and compostable, but it is highly stiff and brittle. The incorporation of NR or ENR to PLA increases the impact strength and toughness of PLA. However, the disparity in polarity between PLA and elastomer phase like NR and ENR results in TPE blend being incompatible. Hence, compatibilization is essential to improve its polarity and develop interactions. Compatibilizer that composed of two different polymer is known is graft compatibilizer with the aid of grafting agent. The graft compatibilizers are divided into two categories. The first type is made up of one polymer and grafting agent and, the other one is composed of two polymer groups and grafting agent. These two types of graft compatibilizer can be prepared via two different method such as direct melt blending and solution. Apart from this, the TPE blend is produced via the melt blending technique with mixing machines such as internal mixer and extruder. This article has reviewed the preparation of the graft compatibilizer and blending technique of TPE. Based on the findings, the graft compatibilizers has a significant role in improving miscibility and compatibility across blend composed of different phase.

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Effect of zinc oxide surface treatment concentration and nanofiller loading on the flexural properties of unsaturated polyester/kenaf nanocomposites

2023-09-01 , Mohammed M. , Oleiwi J.K. , Jawad A.J.a.M. , Mohammed A.M. , Azlin Fazlina Osman , Rozyanty Rahman , Tijjani Adam , Betar B.O. , Subash Chandra Bose Gopinath , Dahham O.S.

Due to environmental concerns and budgetary constraints associated with synthetic fibers, natural fibers (NFr) are becoming increasingly popular as reinforcement in polymer composites (PCs) for structural components and construction materials. The surface treatment (ST) method is a well-established technique for enhancing the strength of interfacial bonding between NFr and the polymer matrix (PM). As a result, this research aims to determine the effect of ST with zinc oxide nanoparticles (ZnONPs) on the flexural properties of unsaturated polyester (UPE)/kenaf fiber (KF) nanocomposites. The hand lay-up technique was employed to produce KF-reinforced unsaturated polyester composites (KF/UPE) for this investigation. UPE/KF-ZnONPs composites were made with varying NFr loadings (weight percent), ranging from 10 to 40%. KF was treated with five distinct amounts of ZnONPs (from 1 to 5% weight percent). According to the findings of the investigation, the composite samples incorporating ZnONPs displayed superior optimum flexural properties compared to the untreated KF composite. It was found that 2% ZnONPs was optimal, and ST with ZnONPs could produce robust KF with improved flexural properties.

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Potential of Rapid Tooling in rapid heat cycle molding: a review

2022 , Nurul Hidayah Mohamad Huzaim , Shayfull Zamree Abd. Rahim , Luqman Musa , Abdellah El-hadj Abdellah , Mohd. Mustafa Al Bakri Abdullah , Allan Rennie , Rozyanty Rahman , Sebastian Garus , Katarzyna Błoch , Andrei Victor Sandu , Petrica Vizureanu , Marcin Nabiałek

Rapid tooling (RT) and additive manufacturing (AM) are currently being used in several parts of industry, particularly in the development of new products. The demand for timely deliveries of low-cost products in a variety of geometrical patterns is continuing to increase year by year. Increased demand for low-cost materials and tooling, including RT, is driving the demand for plastic and rubber products, along with engineering and product manufacturers. The development of AM and RT technologies has led to significant improvements in the technologies, especially in testing performance for newly developed products prior to the fabrication of hard tooling and low-volume production. On the other hand, the rapid heating cycle molding (RHCM) injection method can be implemented to overcome product surface defects generated by conventional injection molding (CIM), since the surface gloss of the parts is significantly improved, and surface marks such as flow marks and weld marks are eliminated. The most important RHCM technique is rapid heating and cooling of the cavity surface, which somewhat improves part quality while also maximizing production efficiencies. RT is not just about making molds quickly; it also improves molding productivity. Therefore, as RT can also be used to produce products with low-volume production, there is a good potential to explore RHCM in RT. This paper reviews the implementation of RHCM in the molding industry, which has been well established and undergone improvement on the basis of different heating technologies. Lastly, this review also introduces future research opportunities regarding the potential of RT in the RHCM technique.

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Interfacial Bonding Mechanisms of Natural Fibre-Matrix Composites: An Overview

2022-01-01 , Mohammed M. , Rasidi M.S.M. , Mohammed A.M. , Rozyanty Rahman , Azlin Fazlina Osman , Tijjani Adam , Betar B.O. , Dahham O.S.

The development of natural fiber (NFr) composites for a variety of applications is on the rise. The optimization of the interfacial bonding (IFB) between the reinforcing NFr and polymer matrix is perhaps the single most critical aspect in the development of natural fibre polymer composites (NFPCs) with high mechanical performance. While the IFB is critical in determining the mechanical properties of the NFPCs, such as stress transfer, it is one of the least understood components. This article offers a summary of IFB mechanisms, different modification approaches targeted at lowering incompatibility and improving IFB, and evaluation of the impact of IFB. It has been found that 1) In general, interdiffusion, electrostatic adhesion, chemical reactions, and mechanical interlocking are accountable for the IFB; 2) the incompatibility of the fibre and matrix, which results in poor dispersion of the fiber, weak IFB, and ultimately worse composite quality, may be addressed through strategic modifications; and 3) Interfacial interactions between polymers and nanoparticles (NPs) are significantly improving their performance in areas like thermal, mechanical, robust IFB, and moisture absorption. As a result, this review study could be an important resource for scholars interested in coating and treating NFr to further enhance their surface characteristics.

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Sensitivity of Chitosan Film Based Electrode Modified with Reduced Graphene Oxide (rGO) for Formaldehyte Detection Using Cyclic Voltammetry

2024 , Irwana Nainggolan , Harry Saisa , Zul Agusnar , Sagir Alfian , Tulus Ikhsan Alva , Rozyanty Rahman , Ardiansyah Rahman

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