Ragunathan Al Santiagoo
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Preferred name
Ragunathan Al Santiagoo
Official Name
Ragunathan, Al Santiagoo
Alternative Name
Ragunathan, Santiagoo
Ragunathan, S.
Santiagoo, R.
Main Affiliation
Scopus Author ID
36619090500
Researcher ID
AGS-2453-2022

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Potential of pretreated palm kernel shell on pyrolysis

2023-01-01 , Razi Ahmad , Ragunathan Al Santiagoo , Abdul Ghapar Ahmad , Syakirah Afiza Mohammed , Wan Ahmad W.A.M. , Vikneswaran Vijean , Ibrahim N.R.

The impact of pretreatment on palm kernel shell (PKS) with torrefaction for the possibility of pyrolysis is discussed in this study. PKS samples were torrefied at different holding times of 30 and 60 minutes at temperatures of 200, 225, 250, 275, and 300 °C. In a fixed-bed reactor with a constant nitrogen flow rate of 500 ml/min, torrefaction pretreatment was carried out. The elemental composition, mass, and energy yield, as well as proximate analysis, were all performed on the pretreated PKS. The optimised pretreated PKS was pyrolyzed next at a temperature of 400 to 550 °C in a fixed-bed reactor. The outcomes demonstrated that the pretreated PKS had a significant mass and energy yield at a temperature of 250 °C and a holding time of 30 min. PKS's calorific value and carbon content both rose after pretreatment. However, the oxygen and moisture content decreased for pretreated PKS. The maximum bio-oil production of 58% was achieved during the pyrolysis of pretreated PKS at a temperature of 500 °C. At higher temperature of 550 ℃, the bio-oil decreased due to secondary cracking reaction. Consequently, the pretreated PKS has greater potential as effective feedstock for successive proses particularly pyrolysis for bio-oil production.

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Influence of pretreated coconut shell on gasification product yield

2023-10-16 , Muda S.Z. , Razi Ahmad , Syakirah Afiza Mohammed , Wan Amiza Amneera Wan Ahmad , Vikneswaran Vijean , Ibrahim N.R. , Ani A.Y. , Ragunathan Al Santiagoo

Gasification of untreated and pretreated coconut shell (CS) was carried out in a fixed-bed reactor to assess the effect of temperature (600, 650, 700, 750, and 800 C) and holding time (30 and 40 min) on gases composition. The untreated CS was first torrefied in a fixed-bed reactor at different temperatures (200 â 300 C) and holding times (30 min, 60 min and 90 min). Pretreated CS at the optimal torrefaction temperature (275 C and 60 min) was used for gasification. Under optimal conditions of 750 C and 30 min holding time, gasification contributed the most gas production. At this optimum condition, the gas composition of pretreated CS was 35.03 % of CH4, 24.43 % of CO2, and 40.54 % of H2 + CO. Untreated CS contains 37.63 % of CH4, 24.03 % of CO2, and 38.34 % of H2 + CO gases. The production of CH4 gas was higher when untreated CS was used for gasification rather than pretreated CS. Moreover, when untreated CS was used for gasification, the amount of CO2, H2, and CO produced was minimal. Therefore, for high H2 production, pretreatment prior to gasification is appropriate.

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Compatibilizers Effect on Recycled Acrylonitrile Butadiene Rubber with Polypropylene and Sugarcane Bagasse Composite for Mechanical Properties

2023-10-16 , Zainal M. , Ragunathan Al Santiagoo , Razi Ahmad , Mohammed S.A. , Abdul Ghapar Ahmad , Vikneswaran Vijean , Wan Amiza Amneera Wan Ahmad , Allan Melvin Andrew

Compatibilizers effect on recycled acrylonitrile butadiene rubber (NBRr) with polypropylene (PP) and sugarcane bagasse (SCB) composite for mechanical properties is evaluated. Trans-Polyoctylene Rubber (TOR) and Bisphenol a Diglycidyl Ether (DGEBA) are used as compatibilizers in this study. Three (3) different composites (80/20/15, 60/40/15, and 40/60/15), with fixed filler (15 phr) and compatibilizers (10 phr) content, were carried out. These composites were arranged via melt mixing technique utilizing a heated two-roll mill at a temperature of 180 C for 9 minutes employing a 15-rpm rotor speed. Tensile and morphological properties were evaluated. The result shown average tensile strength dropped by 48.50% as the recycle NBR content rises 20 phr. Nevertheless, subsequent compatibilization reveals that the compositesâ tensile properties were all greater than control composites. The morphology discovered validates the tensile properties, indicating a stronger interaction between the PP/SCB and recycle NBR composites with the addition of compatibilizer DGEBA.

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Influence of Torrefaction on Sewage Sludge

2023-01-01 , Razi Ahmad , Abdul Ghapar Ahmad , Mohammed S.A. , Wan Ahmad W.A.M. , Vikneswaran Vijean , Ragunathan Al Santiagoo , Ibrahim N.R. , Udin N.

Sewage sludge (SS) from sewage treatment plants has been seen as a waste for decades and little attention to investigate the potential and its beneficial product. SS contain a large amount of recoverable energy; however, it has high moisture, ash, heavy metals, and organic contents. Thus, the goal of this research is to use torrefaction to produce upgraded or torrefied SS. The proximate and ultimate analysis was used to determine the physical and chemical characteristic of raw SS. Torrefaction was performed through inert atmosphere in fixed bed reactor. According to the findings, at torrefaction temperature of 300 °C, torrefaction had improved the quality of raw SS, increasing its fixed carbon content by 47.8%, and its moisture content by 61.3%. The optimum temperature for torrefaction was at 300 ℃ with holding time of 60 minutes. This study improved the quality of sewage sludge to be utilised in subsequent thermochemical conversion.

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The effect of stearic acid and different loading treated and untreated EFB fiber on the tensile, structural and chemical properties of polypropylene/ recycled acrylonitrile butadiene rubber/ empty fruit bunch composites

2021-05-24 , Ragunathan Al Santiagoo , Hong T.W. , Nik Zainab Nik Azizan , Allan Melvin Andrew , Wahab F. , Nor Amirah Abu Seman @ Haji Ahmad , Othman N.S.

A new developed of polymer materials made up of polypropylene (PP), recycled nitrile gloves (NBRr) and empty fruit bunch (EFB) fiber was fabricated. Recycled nitrile glove was blended together with PP plastic to reduce the use of petroleum based and to solve the issue of waste discarded at the landfill. EFB fiber was incorporated to lower the production cost of composite. Due to incompatibility of different phases, stearic acid treatment was used to improve the EFB fiber polarity. Thus, the effect of different EFB loading for untreated and treated stearic acid of PP/NBRr/EFB composite was studied. In this work, all the materials were mixed well using a heated two roll mill with temperature 180 °C within 9 minutes. The EFB loading were varied from 0 to 30 phr. The analysis of tensile properties was tested followed the ASTM D638, Type IV, testing procedure, to analyze tensile strength, Young’s modulus and elongation at break. The structural properties of the fracture sample surfaces were observed using Scanning Electron Microscope (SEM) and the chemical properties was analyzed using Fourier Transform Infra-Red (FTIR). Composites with stearic acid treatment have shown higher tensile strength compared to untreated EFB fiber. Besides, the micrograph structure surface from scanning electron microscopy analysis showed better fiber and matrix interaction, as the treated-EFB fiber is well encapsulated with the PP matrix. From the FTIR analysis, the intensity peak of OH for PP/NBRr/EFB/SA was reduced due to the removal O-H bond of cellulose from fibers during the surface modification of fibers.

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Bio-Char And Bio-Oil Production From Pyrolysis of Palm Kernel Shell And Polyethylene

2023-01-01 , Ibrahim N.R. , Razi Ahmad , Wan Amiza Amneera Wan Ahmad , Vikneswaran Vijean , Ragunathan Al Santiagoo , Syakirah Afiza Mohammed , Khalid A.F. , Ani A.Y.

In recent years, palm kernel shell (PKS) has become a viable feedstock for making biofuels and value-added commodities using a variety of thermal conversion routes. Therefore, significant conservation is required for PKS as a resource for fuel production in biofuel facilities. Thus, this research was intended to elucidate the effects on PKS as a solid fuel through torrefaction and the production of bio-char and bio-oil by single and co-pyrolysis of PKS and polyethylene (PE). The PKS was treated through torrefaction at different temperatures and holding times. The optimum parameters for torrefaction were a temperature of 250 oC and a holding time of 60 min. Then the PKS and PE were pyrolyzed in a fixed-bed reactor at different temperatures and ratios. The product yield was analysed for single and co-pyrolysis of PKS and PE for pyrolysis. The properties of the product composition for single and co-pyrolysis of the PKS and PE were determined by proximate analysis, Fourier transform infrared (FTIR) analysis, and gas chromatography-mass spectrometry (GC-MS). The optimum parameter obtained for biochar and bio-oil production from co-pyrolysis of PKS and PE was at temperature of 500 oC at a ratio of 1:2 (PKS: PE). The ester and phenol compounds were increased around 19.02 to 23.18% and 32.51 to 34.80 %, respectively, while amide and amine decreased around 4.94 to 18.87% and 0.63 to 32.39 %, respectively, compared to the single pyrolysis of PKS. Therefore, the PKS and PE co-pyrolysis significantly increased the amount of phenol and ester compounds while slightly reducing the amount of amide and amine compounds in the bio-oil product. As a conclusion, biomass conservation enables the manufacturing of value-added chemicals.

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