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Ong Hui Lin
Preferred name
Ong Hui Lin
Official Name
Ong, Hui Lin
Alternative Name
Ong, Huilin
Ong, H. L.
Lin, Ong Hui
Lin, O. H.
Lin Ong, Hui
Main Affiliation
Scopus Author ID
57189322712
Researcher ID
F-5201-2010
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1 - 5 of 5
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PublicationGreen synthesis and characterization of Graphene quantum dots from key lime juice(Springer, 2023)
;Nur Atirah Afifah Sezali ;Siew Suan Ng ; ;Al Rey Villagracia ;Ruey-An DoongGraphene quantum dots (GQDs) are one of the members of graphene family with unique properties such as quantum confinement effect, photoluminescence effect, and strong conductivity. This work prepared the GQDs using lime juice obtained from the waste of locally grown key limes as the precursor. The hydrothermal method was used in the preparation of the GQDs. The fluorescence effect of the GQDs was observed under a UV lamp irradiation while other characterization was conducted using high-resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), X-ray powder diffraction (XRD), and Raman spectroscopy. The GQD preparation was successful with the emission of a strong blue color when the GQD was put under a 365 nm UV light irradiation. It was found that the particle size of the prepared GQDs was in the range of 0.7–2.8 nm with an average diameter of 1.3 ± 0.5 nm. The characterization results proved the formation of GQDs as one of the graphene nanomaterials. -
PublicationRevealing the water resistance, thermal and biodegradation properties of Citrus aurantifolia crosslinked Tapioca Starch/Nanocellulose bionanocompositesMoisture absorption, thermal and biodegradation properties of nanocellulose (NC) reinforced bionanocomposite tapioca starch (TS) films crosslinked with Citrus aurantifolia or lime juice (LJ) were investigated for food packaging applications. The films were synthesized by solvent casting using different amounts of nanocellulose and crosslinkers: lime juice and a commercial citric acid (CA). Nanocellulose as reinforcing filler was obtained from oil palm empty fruit bunches through acid hydrolysis. Crystallinity of all TS bionanocomposites was determined using X-ray diffractometry. TS bionanocomposites interaction with water was studied by means of moisture absorption, moisture content and swelling. Flory-Huggin model was used to measure the crosslinked density of crosslinked TS bionanocomposites which indicated successful crosslinking using LJ and CA for TS. The crystallinity of TS film increased from 43.5% for neat TS to 51.6% for TS film with inclusion of NC. LJ-crosslinked TS film with 1 wt% of NC (based on starch content) had the lowest moisture absorption and swelling ratio. TS bionanocomposites with LJ had better thermal and biodegradation properties compared to commercial CA-crosslinked TS biocomposites, which can be a potential food packaging material among the tested bionanocomposites.
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PublicationChemical reactivity and bioactivity properties of pyrazinamide analogs of acetylsalicylic acid and salicylic acid using conceptual density functional theoryConventional drugs used to treat Tuberculosis (TB) are becoming ineffective due to the occurrence of multiple drug resistant strains of tuberculosis (TB). This has made the TB disease a a serious global health dilemma. Hence, there is desperate necessity for the advancement of new drugs. In this work, the chemical reactivity and bioactivity of several analogs ofpyrazinamide (PZA) were investigated. PZA is one of the first-line of drugs used to treat tuberculosis and is a key contributor to shortening the treatment time for the disease. Chemical reactivity descriptors of pyrazinamide (PZA) and its analogs of acetylsalicyclic acid and salicyclic acid were investigated using conceptual density functional theory in water as a solvent at the MN12SX/Def2TZVP level of theory. Results have shown that all PZA analogs have improved their global and local reactivity indeces as compared to pyrazinamide based on its electronegativity, electrodonating power, electroaccepting power, eletrophilicity, global hardness and dual descriptor condensed fukui indexes. Moreover, their pKa values are slightly higher than PZA. In terms of its drug-likeness, all PZA analogs passed the Lipinski's Rule of Five criteria. Furthermore, their bioactivity scores are significantly better than pyrazinamide indicating good reaction to G-Protein Coupled Receptor (GPCR) ligands, kinase inhibitors, ion channel modulators, nuclear receptor ligands, protease inhibitors and other enzyme targets. Overall, the PZA analogs are found to be promising anti-tuberculosis drugs. Based on global and local reactivity descriptors, pKa and bioactivity scores, PZA analog of 5-n-Octanoylsalicylic acid is the most reactive among the PZA analogs tested.
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PublicationOne-pot preparation of highly porous paddy waste derived-cellulose-silica nanocomposite membrane separator for advanced performances of supercapacitor(Springer, 2023)
;Md. Asadul Islam ; ;Nur Atirah Afifah Sezali ;Al Rey Villagracia ;Hai Linh Tran ;Chih-Yi Yeh ;Cheng-Kuo TsaiRuey-an DoongA new strategy was demonstrated to produce cellulose nanofibril-silica (CNF–SiO2) nanocomposite membrane separator for supercapacitor by one-pot synthesis of silica (SiO2) nanoparticles using different contents of tetraethyl orthosilicate (TEOS) precursor (0.9, 1.8, 2.7, 3.6 wt%). With the SiO2 nanoparticles acting as the disassembling agent, a highly porous CNF–SiO2 nanocomposite membrane was prepared using a simple solvent casting method. The CNF–SiO2 nanocomposite membrane with 1.8 wt% TEOS content (CNF-C2), exhibited the best properties with high porosity of 61%, electrolyte uptake ability of 260% and ionic conductivity of 5.0 mS cm− 1. Besides, the maximum thermal degradation temperature (Tmax) of the CNF–SiO2 nanocomposite membrane increased from 300 ℃ to 322 ℃, making it suitable for use within the operating temperatures of a supercapacitor. A symmetric supercapacitor assembled with CNF-C2 separator achieved the highest specific capacitance of 179.0 F g− 1 at 0.1 A g− 1 and energy density of 35.8 Wh kg− 1 at a power density of 240.0 W kg− 1. This CNF–SiO2 nanocomposite membrane helped the supercapacitor to achieve excellent electrochemical stability after 10,000 charge-discharge cycles with a capacitance retention and coulombic efficiency of 98.3% and 95.0%, respectively. The presented results proved that the CNF–SiO2 nanocomposite membrane is a good alternative separator in the supercapacitor application.12 1 -
PublicationPreparation and characterization of cellulose acetate from rice straw(Springer, 2023)
;Nur Atirah Afifah Sezali ; ; ;Nora Jullok ;Maria Carla Manzano ;Al Rey VillagraciaRuey-an DoongRice straw is one of the agricultural crop residues, and it can be utilized for its rich cellulose content. This work extracted cellulose from the locally collected rice straw and prepared the cellulose acetate from the rice straw-derived cellulose. The cellulose was isolated by an extraction process using an alkaline deep eutectic solvent, followed by bleaching to remove lignin and hemicellulose, and lastly the purification of cellulose for efficient acetylation process. The prepared cellulose acetate was characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray powder diffraction (XRD), and differential scanning calorimetry (DSC) to confirm the successful acetylation of cellulose. The properties of the prepared cellulose acetate were compared with the commercial cellulose acetate. The FTIR result confirmed the replacement of hydroxyl groups on cellulose structure by the acetyl groups while the XRD analysis has resulted in the crystallinity index of 25.7% for the prepared cellulose acetate. As one of the cellulose derivatives, the cellulose acetate prepared from the rice straw-derived cellulose showed better thermal properties as the melting temperature was found to be more than 300 °C.1 11