Now showing 1 - 10 of 21
  • Publication
    Mechanical properties and water absorption behaviour of hybrid fibre with recycle high density polyethylene bio-composite
    Hybrid fibre which is rice husk (RH) and softwood were used as organic fibre with different compositions which are 10%, 20% and 30%. Whereas polymer matrix that used in this project is recycled high density polyethylene (r-HDPE) and ethylene glycidyl methacrylate (EGMA) used as compatibilizer in the composite. These materials were pre-mixed using a twin screw extruder and then shaped using hot compression in order to obtain a dumbbell and rectangular shape for Izod impact test, tensile and flexural test using Instron machine. Another test was carried out with a focus to observe the behaviour of water absorption in the composite. Testing resulted in decreasing tensile strength, elongation at break and impact stress upon an increase of fibre content. However, there are slight increases in the result of Young's modulus, water absorption, flexural strength and modulus.
  • Publication
    Comparison between the Tensile, Water Absorption and Flammability Properties of Recycled High-Density Polyethylene/Rice Husk Composite from Twin-Screw Extruder and Heated Two-Roll Mill
    This study compares the mechanical properties of recycled high-density polyethylene (r-HDPE)/rice husk (RH) composites from a twin-screw extruder and a heated two-roll mill, and the effect of different filler loadings using different melt blending processes on the mechanical properties of r-HDPE/RH composites. Polyethylene-graft-maleic anhydride (MAPE) acts as the coupling agent to enhance interfacial bonding between the fibre and the polymer matrix. The filler loading used was in the range of 10-40 wt. %. In this work, r-HDPE/RH blends were prepared using a twin-screw extruder and a heated two-roll mill. The ratio of 70/30 twin-screw extruder compounded composites significantly showed higher tensile based on improved to about 45.5% at 11 MPa compared to those compounded in the heated two-roll mill. The same ratio showed an increment almost up to 9% of elongation at break. It has also been verified that the higher filler loading used reduced the tensile strength and elongation at break, while the Young's modulus increased. The result was evidenced by the increase in water absorption and longer burning time as the filler loading increased.
  • Publication
    Asas Polimer
    Buku asas polimer merupakan sebuah buku yang membincangkan beberapa perkara asas yang utama dalam bidang polimer. Kebanyakan kita mengetahui tentang polimer tetapi tidak pada asas dan sifat semulajadi bahan polimer tersebut. Polimer kini lebih bernilai dan diperlukan dalam bidang binaan, angkasa lepas, komunikasi, pembuatan, pengangkutan, perubatan dan lain-lain keperluan harian. Polimer yang wujud secara semulajadi termasuklah bahan yang kita guna sebagai tar, syelek, getah pokok dan lain-lain menuntut kepada kita untuk memahami dengan lebih jelas ciri-ciri dan sifat bahan polimer. Buku ini dapat memenuhi keperluan dan minat terutamanya pelajar-pelajar untuk memahami dengan lebih mendalam lagi mengenai asas-asas dan sifat-sifat bahan polimer. Tajuk-tajuk yang dibincangkan di dalam buku ini disusun dan dioleh degan cara yang mudah untuk pengajaran dan pembelajaran tentang asas-asas polimer. Buku ini sesuai dijadikan sebagai bahan rujukan asas pelajar-pelajar kejuruteraan bahan, kejuruteraan polimer, teknologi polimer dan sains. Ia juga merangkumi beberapa subjek asas yang penting dalam bidang polimer termasuk kimia polimer, struktur fizikal polimer, reologi polimer, aplikasi, sifat dan pengujian polimer.
      2  27
  • Publication
    Infrared spectroscopy of extracted and acetylated chitin in versatile deep eutectic solvents (DES)
    The conventional method to extract the chitin content from the crustacean shells usually uses concentrated acids and alkalis to remove impurities such as calcium carbonate and protein. However, the uses of concentrated acids and alkalis have caused many environmental issues. Deep Eutectic Solvent (DES) is one of the solvents that can be used to extract the chitin content from the crustacean shells. DES has two components namely Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA). In this study, two types of DES have been used are betaine (HBA) - urea (HBD) and choline chloride (HBA) - urea (HBD). The results showed that DES betaine - urea and choline chloride - urea have extracted chitin content of 5.4609 % and 2.0020 % w/w respectively. The extracted chitins were analyzed using infrared spectroscopy method. The values of the degree of acetylation (DA) for the chitins were 103.1699 and 83.4821 respectively.
      31  3
  • Publication
    Isolation and characterization of microcrystalline cellulose extracted from banana fiber in poly(lactic acid) biocomposite produced from solvent casting technique
    ( 2020-11-24) ;
    Vesuanathan, Tamil Arasi
    ;
    The purpose of this project is to extract Microcrystalline Cellulose (MCC) from Banana fiber to produce Poly(Lactic Acid)/Microcrystalline Cellulose, (PLA/MCC) biocomposite film using a solvent casting technique. The initial phase is the production of MCC from Banana fiber by involving three steps; alkaline treatment, bleaching and acid hydrolysis. MCC produced from the different concentration of Nitric acid in the acid hydrolysis process, were used to analyze the morphological and crystalline properties using SEM and XRD respectively. MCC produced from the higher concentration of Nitric acid shows good morphological properties and higher % crystallinity. Then, MCC compounded into PLA with different filler loading to produce PLA/MCC biocomposite film using a different solvent which is Chloroform and Dichloromethane. Results show that lower MCC loading, induces good filler matrix interaction and this evidences by the improvement of the Tensile strength and Young's Modulus, as well as shows improvement in loss factor and storage modulus which studied from DMA. Moreover, the addition of MCC slightly improved the thermal stability of PLA. From using a different solvent to produce PLA/MCC biocomposite film, Dichloromethane solvent improves the tensile strength and Young's modulus of biocomposite film, while Chloroform reduces the tensile properties of biocomposite film.
      3  18
  • Publication
    Determination of degree of acetylation (DA) for chitin in deep eutectic solvents (DES)
    Degree of acetylation (DA) is an important parameter to determine the quality of chitin. Apart from the assessment on the bond structure in the chitin molecule, infrared spectroscopy is one of the methods that can be used to determine the value of DA. The DA value of chitin is an important parameter because the value indicates the purity of chitin quality. Chitin acetylation is the process of addition an acetyl substitution group (-COCH3) to a chitin chain. The addition of acetyl will improve its dispersing properties and subsequently will improve the chitin adhesion properties within hydrophobic matrix in composite materials as well. In this study, Deep Eutectic Solvent (DES) was used as a medium for chitin extraction and acetylation in one single process. DES has two components namely Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA). Betaine and choline chloride were used as HBA whilst urea was selected to be utilized as HBD. The findings showed that the quantity of extracted chitins by the DESs were 5.4609 % and 2.0020 % respectively. The DA values for the extracted chitins are 103.1699 and 83.4821. For acetylated chitin in DES betaine - urea, the DA value was increased from 103.1699 to 118.4818. The findings showed that the high quality acetylated chitin can be produced in a single process involving extraction and acetylation process by using DES as a medium.
      26  1
  • Publication
    A review on graft compatibilizer for thermoplastic elastomer blend
    A biodegradable thermoplastic elastomer (TPE) blend is developed by blending poly (lactic acid) (PLA) and natural rubber (NR) or epoxidized natural rubber (ENR) and it is a sustainable substitution in recent years for synthetic polymers. PLA is high in mechanical strength and compostable, but it is highly stiff and brittle. The incorporation of NR or ENR to PLA increases the impact strength and toughness of PLA. However, the disparity in polarity between PLA and elastomer phase like NR and ENR results in TPE blend being incompatible. Hence, compatibilization is essential to improve its polarity and develop interactions. Compatibilizer that composed of two different polymer is known is graft compatibilizer with the aid of grafting agent. The graft compatibilizers are divided into two categories. The first type is made up of one polymer and grafting agent and, the other one is composed of two polymer groups and grafting agent. These two types of graft compatibilizer can be prepared via two different method such as direct melt blending and solution. Apart from this, the TPE blend is produced via the melt blending technique with mixing machines such as internal mixer and extruder. This article has reviewed the preparation of the graft compatibilizer and blending technique of TPE. Based on the findings, the graft compatibilizers has a significant role in improving miscibility and compatibility across blend composed of different phase.
      2
  • Publication
    The influence of MMA esterification on interfacial adhesion and mechanical properties of hybrid kenaf bast/glass fiber reinforced unsaturated polyester composites
    ( 2021) ;
    Syed Zhafer Firdaus Syed Putra
    ;
    ;
    Irwana Nainggolan
    ;
    Bartłomiej Jeż
    ;
    Marcin Nabiałek
    ;
    ;
    Andrei Victor Sandu
    ;
    Petrica Vizureanu
    ;
    ;
    Dariusz Kwiatkowski
    ;
    Izabela Wnuk
    The demand for natural fiber hybrid composites for various applications has increased, which is leading to more research being conducted on natural fiber hybrid composites due to their promising mechanical properties. However, the incompatibility of natural fiber with polymer matrix limits the performance of the natural fiber hybrid composite. In this research work, the mechanical properties and fiber-to-matrix interfacial adhesion were investigated. The efficiency of methyl methacrylate (MMA)-esterification treatments on composites’ final product performance was determined. The composite was prepared using the hand lay-up method with varying kenaf bast fiber (KBF) contents of 10, 15, 20, 25, 30, 35 (weight%) and hybridized with glass fiber (GF) at 5 and 10 (weight%). Unsaturated polyester (UPE) resin and methyl ethyl ketone peroxide (MEKP) were used as binders and catalysts, respectively. Scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR) were used to examine the effects of MMA-esterification treatment on tensile strength and morphology (tensile fracture and characterization of MMA-esterification treatment) of the composite fabricated. The tensile strength of MMA-treated reinforced UPE and hybrid composites are higher than that of untreated composites. As for MMA treatment, 90 min of treatment showed the highest weight percent gain (WPG) and tensile strength of KBF-reinforced UPE composites. It can be concluded that the esterification of MMA on the KBF can lead to better mechanical properties and adhesion between the KFB and the UPE matrix. This research provides a clear reference for developing hybrid natural fibers, thus contributing to the current field of knowledge related to GF composites, specifically in transportation diligences due to their properties of being lightweight, superior, and involving low production cost.
      10  14
  • Publication
    Electrochemical Impedance Spectroscopy (EIS) study of coconut water as natural inhibitor in Malay traditional preservation of iron artefact
    (IOP Publishing, 2020)
    M. Musa
    ;
    Hadi Purwanto
    ;
    R. Razak
    ;
    R. Othman
    ;
    ;
    MH Ani
    Treating and cleaning corroded artefact has resulted in long-term loss of artefact integrity and intangible historical value in museum preservation method. Inhibitors and coatings are preferable methods applied in heritage conservation as it is the easiest way for corrosion protection. However, issue of health and environment has led conservators to find a better inhibitor, natural or green corrosion inhibitors. Surprisingly, Malay traditional practice has since long ago used Coconut water (CW) as corrosion inhibitor to preserve keris blades, showing that the knowledge in corrosion protection has been practiced in old Malay civilization for metal preservation. This paper intends to clarify the compositional effect of CW in the inhibition efficiency to iron-based keris blade. Through Tafel and Electrochemical Impedance Spectroscopy (EIS) and Energy dispersive analysis of X-rays (EDAX) analysis, the study showed that CW formed passivation with the highest IE of 92% as compared to other natural inhibitors existing and used in industries such as Ascorbic Acid (AA) and Tartaric acid (TA). EIS and Scanning Electron Microscope (SEM) study has shown and conclude that CW has displayed protective abilities that exceeds both AA and TA.
      2  4
  • Publication
    Sifat bahan plastik
    ( 2011) ;
    Che Mohd Ruzaidi Ghazali
    ;
    ;
    Buku ini secara khusus mengutarakan dengan lengkap tentang sifat dan ciri bahan plastik melalui beberapa bab dalam buku ini dan kaedah dan prinsip pengujian serta perincirian bahan plastik. Buku ini boleh membantu pelajar dan pembaca dalam mengenalpasti perbezaan jenis-jenis bahan plastik dan memahami konsep hubung kait di antara struktur dan sifat-sifat bahan plastik.
      4  448