Mohd. Mustafa Al Bakri Abdullah
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Preferred name
Mohd. Mustafa Al Bakri Abdullah
Official Name
Abdulah, Mohd. Mustafa Al Bakri
Alternative Name
Abdullah, M.M.A.
M.M.A. Abdullah
Mustafa Al Bakri, A. M.
Albakri Abdullah, M. M.
Main Affiliation
CeGeoGTech UniMAP
Scopus Author ID
53164519100

Research Output
Now showing 1 - 4 of 4
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Publication

Improvements of flexural properties and thermal performance in thin geopolymer based on fly ash and ladle furnace slag using borax decahydrates

2022 , Ng Yong-Sing , Liew Yun Ming , Heah Cheng Yong , Mohd. Mustafa Al Bakri Abdullah , Phakkhananan Pakawanit , Petrica Vizureanu , Mohd Suhaimi Khalid , Ng Hui-Teng , Hang Yong-Jie , Marcin Nabiałek , Paweł Pietrusiewicz , Sebastian Garus , Wojciech Sochacki , Agata Śliwa

This paper elucidates the influence of borax decahydrate addition on the flexural and thermal properties of 10 mm thin fly ash/ladle furnace slag (FAS) geopolymers. The borax decahydrate (2, 4, 6, and 8 wt.%) was incorporated to produce FAB geopolymers. Heat treatment was applied with temperature ranges of 300 °C, 600 °C, 900 °C, 1000 °C and 1100 °C. Unexposed FAB geopolymers experienced a drop in strength due to a looser matrix with higher porosity. However, borax decahydrate inclusion significantly enhanced the flexural performance of thin geopolymers after heating. FAB2 and FAB8 geopolymers reported higher flexural strength of 26.5 MPa and 47.8 MPa, respectively, at 1000 °C as compared to FAS geopolymers (24.1 MPa at 1100 °C). The molten B2O3 provided an adhesive medium to assemble the aluminosilicates, improving the interparticle connectivity which led to a drastic strength increment. Moreover, the borax addition reduced the glass transition temperature, forming more refractory crystalline phases at lower temperatures. This induced a significant strength increment in FAB geopolymers with a factor of 3.6 for FAB8 at 900 °C, and 4.0 factor for FAB2 at 1000 °C, respectively. Comparatively, FAS geopolymers only achieved 3.1 factor in strength increment at 1100 °C. This proved that borax decahydrate could be utilized in the high strength development of thin geopolymers.

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Self-Fluxing mechanism in geopolymerization for Low-Sintering temperature of ceramic

2021 , Noorina Hidayu Jamil , Mohd. Mustafa Al Bakri Abdullah , Faizul Che Pa , Hasmaliza Mohamad , Wan Mohd Arif W Ibrahim , Penphitcha Amonpattaratkit , Joanna Gondro , Wojciech Sochacki , Norfadhilah Ibrahim

Kaolin, theoretically known as having low reactivity during geopolymerization, was used as a source of aluminosilicate materials in this study. Due to this concern, it is challenging to directly produce kaolin geopolymers without pre-treatment. The addition of ground granulated blast furnace slag (GGBS) accelerated the geopolymerization process. Kaolin–GGBS geopolymer ceramic was prepared at a low sintering temperature due to the reaction of the chemical composition during the initial stage of geopolymerization. The objective of this work was to study the influence of the chemical composition towards sintering temperature of sintered kaolin–GGBS geopolymer. Kaolin–GGBS geopolymer was prepared with a ratio of solid to liquid 2:1 and cured at 60 °C for 14 days. The cured geopolymer was sintered at different temperatures: 800, 900, 1000, and 1100 °C. Sintering at 900 °C resulted in the highest compressive strength due to the formation of densified microstructure, while higher sintering temperature led to the formation of interconnected pores. The difference in the X-ray absorption near edge structure (XANES) spectra was related to the phases obtained from the X-ray diffraction analysis, such as akermanite and anothite. Thermal analysis indicated the stability of sintered kaolin–GGBS geopolymer when exposed to 1100 °C, proving that kaolin can be directly used without heat treatment in geopolymers. The geopolymerization process facilitates the stability of cured samples when directly sintered, as well as plays a significant role as a self-fluxing agent to reduce the sintering temperature when producing sintered kaolin–GGBS geopolymers.

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Geopolymer-based nepheline ceramics: effect of sintering profile on morphological characteristics and flexural strength

2022 , Romisuhani Ahmad , Wan Mastura Wan Ibrahim , Mohd. Mustafa Al Bakri Abdullah , Phakkhananan Pakawanit , Petrica Vizureanu , Arman Shah Abdullah , Andrei Victor Sandu , Fakhryna Hannanee Ahmad Zaidi

The focus of this study is the fabrication of innovative and sustainable ceramic-based geopolymer with improved low temperatures performances. Kaolin was mixed with liquid sodium silicate (Na₂SiO₃) and 12M of sodium hydroxide (NaOH) solution using alkali activator ratio of 0.24 and solid-to-liquid ratio of 1:1 to synthesize kaolin geopolymer. The effect of the sintering profile on the microstructure, pore evolution and flexural strength were investigated. The heating exposure aided consolidation and created a fairly uniform microstructure, resulting in a smooth surface texture. In comparison to the unheated geopolymer, 3D pore distribution showed a significant increase in the range size of ~30 µm with the appearance of isolated and intergranular pores. The flexural strength at 1200 °C with a heating rate of 5 °C/min and was increased by 146.4% to 85.4 MPa, as compared to the heating rate of 2 °C/min. The sintering process has an impact on the final microstructure formation thus improving the characteristic of geopolymer-based nepheline ceramic.

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Strength development and elemental distribution of Dolomite/Fly ash geopolymer composite under elevated temperature

2020 , Emy Aizat Azimi , Mohd. Mustafa Al Bakri Abdullah , Petrica Vizureanu , Mohd Arif Anuar Mohd Salleh , Andrei Victor Sandu , Jitrin Chaiprapa , Sorachon Yoriya , Kamarudin Hussin , Ikmal Hakem Aziz

A geopolymer has been reckoned as a rising technology with huge potential for application across the globe. Dolomite refers to a material that can be used raw in producing geopolymers. Nevertheless, dolomite has slow strength development due to its low reactivity as a geopolymer. In this study, dolomite/fly ash (DFA) geopolymer composites were produced with dolomite, fly ash, sodium hydroxide, and liquid sodium silicate. A compression test was carried out on DFA geopolymers to determine the strength of the composite, while a synchrotron Micro-Xray Fluorescence (Micro-XRF) test was performed to assess the elemental distribution in the geopolymer composite. The temperature applied in this study generated promising properties of DFA geopolymers, especially in strength, which displayed increments up to 74.48 MPa as the optimum value. Heat seemed to enhance the strength development of DFA geopolymer composites. The elemental distribution analysis revealed exceptional outcomes for the composites, particularly exposure up to 400 °C, which signified the homogeneity of the DFA composites. Temperatures exceeding 400 °C accelerated the strength development, thus increasing the strength of the DFA composites. This appears to be unique because the strength of ordinary Portland Cement (OPC) and other geopolymers composed of other raw materials is typically either maintained or decreases due to increased heat.

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