Now showing 1 - 3 of 3
  • Publication
    Improvements of flexural properties and thermal performance in thin geopolymer based on fly ash and ladle furnace slag using borax decahydrates
    ( 2022)
    Ng Yong-Sing
    ;
    ; ; ;
    Phakkhananan Pakawanit
    ;
    Petrica Vizureanu
    ;
    Mohd Suhaimi Khalid
    ;
    Ng Hui-Teng
    ;
    Hang Yong-Jie
    ;
    Marcin Nabiałek
    ;
    Paweł Pietrusiewicz
    ;
    Sebastian Garus
    ;
    Wojciech Sochacki
    ;
    Agata Åšliwa
    This paper elucidates the influence of borax decahydrate addition on the flexural and thermal properties of 10 mm thin fly ash/ladle furnace slag (FAS) geopolymers. The borax decahydrate (2, 4, 6, and 8 wt.%) was incorporated to produce FAB geopolymers. Heat treatment was applied with temperature ranges of 300 °C, 600 °C, 900 °C, 1000 °C and 1100 °C. Unexposed FAB geopolymers experienced a drop in strength due to a looser matrix with higher porosity. However, borax decahydrate inclusion significantly enhanced the flexural performance of thin geopolymers after heating. FAB2 and FAB8 geopolymers reported higher flexural strength of 26.5 MPa and 47.8 MPa, respectively, at 1000 °C as compared to FAS geopolymers (24.1 MPa at 1100 °C). The molten B2O3 provided an adhesive medium to assemble the aluminosilicates, improving the interparticle connectivity which led to a drastic strength increment. Moreover, the borax addition reduced the glass transition temperature, forming more refractory crystalline phases at lower temperatures. This induced a significant strength increment in FAB geopolymers with a factor of 3.6 for FAB8 at 900 °C, and 4.0 factor for FAB2 at 1000 °C, respectively. Comparatively, FAS geopolymers only achieved 3.1 factor in strength increment at 1100 °C. This proved that borax decahydrate could be utilized in the high strength development of thin geopolymers.
      3  21
  • Publication
    Evaluation of flexural properties and characterisation of 10-mm thin geopolymer based on fly ash and ladle furnace slag
    ( 2021)
    Ng Yong-Sing
    ;
    ; ; ;
    Lynette Wei Ling Chan
    ;
    Ng Hui-Teng
    ;
    Ong Shee-Ween
    ;
    Ooi Wan-En
    ;
    Hang Yong-Jie
    The formulation and flexural properties of thin fly ash geopolymers with thickness of merely 10 mm and replacement of ladle furnace slag to fly ash in thin geopolymer were presented. The formulation was discussed in terms of NaOH molarity, solid aluminosilicates-to-liquid alkali activator (S/L) mass ratio, and alkali activator (Na2SiO3/NaOH) mass ratio. Thin fly ash geopolymers with flexural strength and Young's modulus of 6.2 MPa and 0.14 GPa, respectively, were obtained by using 12 M NaOH, S/L ratio of 2.5 and Na2SiO3/NaOH ratio of 4.0. A high Na2SiO3/NaOH ratio was implemented for thin geopolymer synthesis to produce a more viscous slurry which helped to retain the shape of a thin geopolymer. The incorporation of ladle furnace slag up to 40 wt.% reported an increment of 26% in flexural strength up to 7.8 MPa as compared to pure fly ash geopolymers and the stiffness was increased to 0.19 GPa. Denser microstructure with improved compactness was observed as the ladle furnace slag acted as the filler. New crystalline phases of calcium silicate hydrate (C–S–H) were formed and coexisted with the geopolymer matrix, which consequently enhanced the flexural strength of thin fly ash geopolymer. This proved that the ladle furnace slag has the potential to be utilised in geopolymer synthesis and will enhance the flexural properties of thin geopolymers. The flexural performance of thin geopolymers in this study was considerably good as the thin geopolymers exhibited comparatively similar flexural strengths, but a higher strength/thickness ratio as compared to geopolymers with thickness greater than 40 mm.
      1  18
  • Publication
    Interaction of silica fume on flexural properties of 10 mm-thickness geopolymers based on fly ash and ladle furnace slag under the thermal conditions
    ( 2023)
    Ng Yong-Sing
    ;
    ;
    Catleya Rojviriya
    ;
    ; ;
    Mohd Suhaimi Khalid
    ;
    Ong Shee-Ween
    ;
    Ooi Wan En
    ;
    Hang Yong Jie
    Studies regarding the properties of geopolymers with silica fume addition at elevated temperature exposure were rarely reported. This paper evaluates the effect of silica fume inclusion on the flexural and thermal performance of geopolymers based on fly ash (FA) and ladle furnace slag (LFS) with thickness of merely 10 mm. Fly ash/slag (FS) geopolymer was prepared by mixing FA and LFS using a weight ratio of 60:40 with an alkali activator (sodium silicate and sodium hydroxide). Silica fume (1, 2, 3, and 4 wt%) was added to prepare FSF geopolymers. The geopolymers were then subjected to the elevated temperature up to 1100 °C after 28-days of curing. Higher flexural strength of 9.1 MPa was achieved in unexposed FSF geopolymers with 3 wt% silica fume addition as compared to unexposed FS geopolymers (7.8 MPa). Flexural strength degraded with higher silica fume content of 4 wt%. Heat treatment significantly improved the flexural strength of geopolymers. Both FS and FSF3 geopolymers had increased strength of 208.9% to 24.1 MPa at 1100 °C and 192.3% to 26.6 MPa at 1000 °C, respectively as compared to the unexposed specimen. The inclusion of silica fume with extreme fineness improved the interconnectivity of the geopolymer matrix, densifying the geopolymer structure and thus enhancing the thermal resistance of geopolymers. However, the dense matrix with low flowability of FSF3 geopolymers could not sustain the high thermal stress and caused strength degradation and crack formation at a high temperature of 1100 °C. Even so, the flexural strength of 1100 °C heat-treated FSF3 geopolymer was 13.2% higher than the unexposed specimen. This demonstrated that silica fume could be incorporated in enhancing the thermal resistance and high strength achievement in geopolymers.
      2