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Characterisation at the bonding zone between fly ash based Geopolymer Repair Materials (GRM) and Ordinary Portland Cement Concrete (OPCC)

2020 , Warid Wazien Ahmad Zailani , Mohd. Mustafa Al Bakri Abdullah , Mohd Fadzil Arshad , Rafiza Abd Razak , Muhammad Faheem Mohd. Tahir , Remy Rozainy Mohd Arif Zainol , Marcin Nabialek , Andrei Victor Sandu , Jerzy J. Wysłocki , Katarzyna Błoch

In recent years, research and development of geopolymers has gained significant interest in the fields of repairs and restoration. This paper investigates the application of a geopolymer as a repair material by implementation of high-calcium fly ash (FA) as a main precursor, activated by a sodium hydroxide and sodium silicate solution. Three methods of concrete substrate surface preparation were cast and patched: as-cast against ordinary Portland cement concrete (OPCC), with drilled holes, wire-brushed, and left as-cast against the OPCC grade 30. This study indicated that FA-based geopolymer repair materials (GRMs) possessed very high bonding strength at early stages and that the behavior was not affected significantly by high surface treatment roughness. In addition, the investigations using scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) spectroscopy have revealed that the geopolymer repair material became chemically bonded to the OPC concrete substrate, due to the formation of a C–A–S–H gel. Fundamentally, the geopolymer network is composed of tetrahedral anions (SiO4)4− and (AlO4)5− sharing the oxygen, which requires positive ions such as Na+, K+, Li+, Ca2+, Na+, Ba2+, NH4+, and H3O+. The availability of calcium hydroxide (Ca(OH)2) at the surface of the OPCC substrate, which was rich in calcium ions (Ca2+), reacted with the geopolymer; this compensated the electron vacancies of the framework cavities at the bonding zone between the GRM and the OPCC substrate.

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Potential of new sustainable green geopolymer metal composite (GGMC) material as mould insert for Rapid Tooling (RT) in injection moulding process

2023 , Allice Tan Mun Yin , Shayfull Zamree Abd. Rahim , Mohd. Mustafa Al Bakri Abdullah , Marcin Nabialek , Abdellah El-hadj Abdellah , Allan Rennie , Muhammad Faheem Mohd. Tahir , Aurel Mihail Titu

The investigation of mould inserts in the injection moulding process using metal epoxy composite (MEC) with pure metal filler particles is gaining popularity among researchers. Therefore, to attain zero emissions, the idea of recycling metal waste from industries and workshops must be investigated (waste free) because metal recycling conserves natural resources while requiring less energy to manufacture new products than virgin raw materials would. The utilisation of metal scrap for rapid tooling (RT) in the injection moulding industry is a fascinating and potentially viable approach. On the other hand, epoxy that can endure high temperatures (>220 °C) is challenging to find and expensive. Meanwhile, industrial scrap from coal-fired power plants can be a precursor to creating geopolymer materials with desired physical and mechanical qualities for RT applications. One intriguing attribute of geopolymer is its ability to endure temperatures up to 1000 °C. Nonetheless, geopolymer has a higher compressive strength of 60–80 MPa (8700–11,600 psi) than epoxy (68.95 MPa) (10,000 psi). Aside from its low cost, geopolymer offers superior resilience to harsh environments and high compressive and flexural strength. This research aims to investigate the possibility of generating a new sustainable material by integrating several types of metals in green geopolymer metal composite (GGMC) mould inserts for RT in the injection moulding process. It is necessary to examine and investigate the optimal formulation of GGMC as mould inserts for RT in the injection moulding process. With less expensive and more ecologically friendly components, the GGMC is expected to be a superior choice as a mould insert for RT. This research substantially impacts environmental preservation, cost reduction, and maintaining and sustaining the metal waste management system. As a result of the lower cost of recycled metals, sectors such as mould-making and machining will profit the most.

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Mechanical and durability analysis of fly ash based geopolymer with various compositions for rigid pavement applications

2022 , Muhammad Faheem Mohd. Tahir , Mohd. Mustafa Al Bakri Abdullah , Shayfull Zamree Abd. Rahim , Mohd Rosli Mohd Hasan , Andrei Victor Sandu , Petrica Vizureanu , Che Mohd Ruzaidi Ghazali , Aeslina Abdul Kadir

Ordinary Portland cement (OPC) is a conventional material used to construct rigid pavement that emits large amounts of carbon dioxide (CO2) during its manufacturing process, which is bad for the environment. It is also claimed that OPC is susceptible to acid attack, which increases the maintenance cost of rigid pavement. Therefore, a fly ash based geopolymer is proposed as a material for rigid pavement application as it releases lesser amounts of CO2 during the synthesis process and has higher acid resistance compared to OPC. This current study optimizes the formulation to produce fly ash based geopolymer with the highest compressive strength. In addition, the durability of fly ash based geopolymer concrete and OPC concrete in an acidic environment is also determined and compared. The results show that the optimum value of sodium hydroxide concentration, the ratio of sodium silicate to sodium hydroxide, and the ratio of solid-to-liquid for fly ash based geopolymer are 10 M, 2.0, and 2.5, respectively, with a maximum compressive strength of 47 MPa. The results also highlight that the durability of fly ash based geopolymer is higher than that of OPC concrete, indicating that fly ash based geopolymer is a better material for rigid pavement applications, with a percentage of compressive strength loss of 7.38% to 21.94% for OPC concrete. This current study contributes to the field of knowledge by providing a reference for future development of fly ash based geopolymer for rigid pavement applications.

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Physical and mechanical studies of kaolin-based geopolymer masonry brick

2015 , Muhammad Faheem Mohd. Tahir

A brick is mainly applied as a building material in construction of walls. Conventional construction bricks are usually made from Portland cement, clay and sand, which are mixed and molded in various method and need to be dried and burned with the temperature range between 900 to 1200 degree centigrade. The drying and firing process takes 2 to 4 days to be done. Other than that, the production of Portland cement consume high energy and can emit 1 to 1.2 ton of carbon dioxide (CO2) for every 1 ton of Portland cement product. Nowadays, a novel family of building materials which is geopolymer cement has seen a great development around the world. It is caused by the environmental issues that pressured the industries to manufacture a products and materials that are more environmental friendly. The aim of this research was to produce a product that would provide an alternative to the conventional bricks with a good properties by utilizing a geopolymer material which is kaolin, reduce the pollution of environment by replacing the usage of Portland cement in brick making industry, and produce effectively usable product by enhance the properties of ordinary product. This study has been conducted to produce kaolin-based geopolymer bricks by means of pressure forming without firing procedure and low energy consumptions.

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Optimizing of the cementitious composite matrix by addition of steel wool fibers (Chopped) based on physical and mechanical analysis

2021 , Akrm A Rmdan Amer , Mohd. Mustafa Al Bakri Abdullah , Liew Yun Ming , Jerzy J. Wysłocki , Wojciech Sochacki , Ikmal Hakem A Aziz , Muhammad Faheem Mohd. Tahir , Sebastian Garus , Joanna Gondro , Hetham A. R. Amer

The demand for durable, resistant, and high-strength structural material has led to the use of fibers as reinforcing elements. This paper presents an investigation into the inclusion of chopped steel wool fibers (CSWFs) in cement to form a high-flexural strength cementitious composite matrix (CCM). CSWFs were used as the primary reinforcement in CCM at increments of 0.5 wt%, from 0.5–6 wt%, with ratios of cement to sand of 1:1.5 and water to cement of 0.45. The inclusion of CSWFs resulted in an excellent optimization of the physicomechanical properties of the CCM, such as its density (2.302 g/cm3), compressive strength (61.452 MPa), and maximum flexural strength (10.64 MPa), all of which exceeded the performances of other reinforcement elements reported in the literature.

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Tool wear and surface evaluation in drilling fly ash geopolymer using HSS, HSS-Co, and HSS-TiN cutting tools

2021 , Mohd Fathullah Ghazli@Ghazali , Mohd. Mustafa Al Bakri Abdullah , Shayfull Zamree Abd. Rahim , Joanna Gondro , Paweł Pietrusiewicz , Sebastian Garus , Tomasz Stachowiak , Andrei Victor Sandu , Muhammad Faheem Mohd. Tahir , Mehmet Erdi Korkmaz , Mohamed Syazwan Osman

This paper reports on the potential use of geopolymer in the drilling process, with respect to tool wear and surface roughness. The objectives of this research are to analyze the tool life of three different economy-grade drill bit uncoated; high-speed steel (HSS), HSS coated with TiN (HSS-TiN), and HSS-cobalt (HSS-Co) in the drilling of geopolymer and to investigate the effect of spindle speed towards the tool life and surface roughness. It was found that, based on the range of parameters set in this experiment, the spindle speed is directly proportional to the tool wear and inversely proportional to surface roughness. It was also observed that HSS-Co produced the lowest value of surface roughness compared to HSS-TiN and uncoated HSS and therefore is the most favorable tool to be used for drilling the material. For HSS, HSS coated with TiN, and HSS-Co, only the drilling with the spindle speed of 100 rpm was able to drill 15 holes without surpassing the maximum tool wear of 0.10 mm. HSS-Co exhibits the greatest tool life by showing the lowest value of flank wear and produce a better surface finish to the sample by a low value of surface roughness value (Ra). This finding explains that geopolymer is possible to be drilled, and therefore, ranges of cutting tools and parameters suggested can be a guideline for researchers and manufacturers to drill geopolymer for further applications.

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Bahan geopolimer : Pemprosesan, Pencirian dan Aplikasi

2015 , Mohd. Mustafa Al Bakri Abdullah , Zarina Yahya , Alida Abdullah , Rafiza Abd Razak , Kamarudin Hussin , Liyana Jamaludin , Muhammad Faheem Mohd. Tahir

Buku Bahan Geopolimer: Pemprosesan, Pencirian dan Aplikasi adalah sebuah buku yang membincangkan beberapa aspek penting mengenai bahan geopolimer seperti pemprosesan, perincian, aplikasi dan sifat bahan geopolimer dalam teknologi konkrit. Buku ini juga menerangkan secara terperinci tentang bahan geopolimer dari aspek teori, pemprosesan, pencirian dan aplikasi yang sesuai dijadikan sebagai bahan rujukan dan panduan kepada pelajar, penyelidik dan pengamal industri.

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Tool wear and surface evaluation in drilling fly ash geopolymer using HSS, HSS-Co, and HSS-TiN cutting tools

2021 , Mohd Fathullah Ghazli@Ghazali , Mohd. Mustafa Al Bakri Abdullah , Shayfull Zamree Abd. Rahim , Joanna Gondro , Paweł Pietrusiewicz , Sebastian Garus , Tomasz Stachowiak , Andrei Victor Sandu , Muhammad Faheem Mohd. Tahir , Mehmet Erdi Korkmaz , Mohamed Syazwan Osman

This paper reports on the potential use of geopolymer in the drilling process, with respect to tool wear and surface roughness. The objectives of this research are to analyze the tool life of three different economy-grade drill bit uncoated; high-speed steel (HSS), HSS coated with TiN (HSS-TiN), and HSS-cobalt (HSS-Co) in the drilling of geopolymer and to investigate the effect of spindle speed towards the tool life and surface roughness. It was found that, based on the range of parameters set in this experiment, the spindle speed is directly proportional to the tool wear and inversely proportional to surface roughness. It was also observed that HSS-Co produced the lowest value of surface roughness compared to HSS-TiN and uncoated HSS and therefore is the most favorable tool to be used for drilling the material. For HSS, HSS coated with TiN, and HSS-Co, only the drilling with the spindle speed of 100 rpm was able to drill 15 holes without surpassing the maximum tool wear of 0.10 mm. HSS-Co exhibits the greatest tool life by showing the lowest value of flank wear and produce a better surface finish to the sample by a low value of surface roughness value (Ra). This finding explains that geopolymer is possible to be drilled, and therefore, ranges of cutting tools and parameters suggested can be a guideline for researchers and manufacturers to drill geopolymer for further applications

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Evaluation on the mechanical properties of Ground Granulated Blast Slag (GGBS) and fly ash stabilized soil via geopolymer process

2021 , Syafiadi Rizki Abdila , Mohd. Mustafa Al Bakri Abdullah , Romisuhani Ahmad , Shayfull Zamree Abd. Rahim , Małgorzata Rychta , Izabela Wnuk , Marcin Nabiałek , Krzysztof Muskalski , Muhammad Faheem Mohd. Tahir , Muhammad Syafwandi , Marek Isradi

This study intended to address the problem of damaged (collapsed, cracked and decreased soil strength) road pavement structure built on clay soil due to clay soil properties such as low shear strength, high soil compressibility, low soil permeability, low soil strength, and high soil plasticity. Previous research reported that ground granulated blast slag (GGBS) and fly ash can be used for clay soil stabilizations, but the results of past research indicate that the road pavement construction standards remained unfulfilled, especially in terms of clay’s subgrade soil. Due to this reason, this study is carried out to further investigate soil stabilization using GGBS and fly ash-based geopolymer processes. This study investigates the effects of GGBS and ratios of fly ash (solid) to alkaline activator (liquid) of 1:1, 1.5:1, 2:1, 2.5:1, and 3:1, cured for 1 and 7 days. The molarity of sodium hydroxide (NaOH) and the ratio of sodium silicate (Na2SiO3) to sodium hydroxide (NaOH) was fixed at 10 molar and 2.0 weight ratio. The mechanical properties of the soil stabilization based geopolymer process were tested using an unconfined compression test, while the characterization of soil stabilization was investigated using the plastic limit test, liquid limit test, scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). The results showed that the highest strength obtained was 3.15 MPA with a GGBS to alkaline activator ratio of 1.5 and Na2SiO3 to NaOH ratio of 2.0 at 7 days curing time. These findings are useful in enhancing knowledge in the field of soil stabilization-based geopolymer, especially for applications in pavement construction. In addition, it can be used as a reference for academicians, civil engineers, and geotechnical engineers.

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Mechanical performance, microstructure, and porosity evolution of fly ash geopolymer after ten years of curing age

2023 , Ikmal Hakem A. Aziz , Mohd. Mustafa Al Bakri Abdullah , Rafiza Abd Razak , Zarina Yahya , Mohd Arif Anuar Mohd Salleh , Jitrin Chaiprapa , Catleya Rojviriya , Petrica Vizureanu , Andrei Victor Sandu , Muhammad Faheem Mohd. Tahir , Alida Abdullah , Liyana Jamaludin

This paper elucidates the mechanical performance, microstructure, and porosity evolution of fly ash geopolymer after 10 years of curing age. Given their wide range of applications, understanding the microstructure of geopolymers is critical for their long-term use. The outcome of fly ash geopolymer on mechanical performance and microstructural characteristics was compared between 28 days of curing (FA28D) and after 10 years of curing age (FA10Y) at similar mixing designs. The results of this work reveal that the FA10Y has a beneficial effect on strength development and denser microstructure compared to FA28D. The total porosity of FA10Y was also lower than FA28D due to the anorthite formation resulting in the compacted matrix. After 10 years of curing age, the 3D pore distribution showed a considerable decrease in the range of 5–30 µm with the formation of isolated and intergranular holes.