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Effect of polyethylene glycol and sodium dodecyl sulphate on microstructure and self-cleaning properties of graphene oxide/TiO2 thin film

2020-09-01 , Azani A. , Dewi Suriyani Che Halin , Kamrosni Abdul Razak , Mohd. Mustafa Al Bakri Abdullah , Norsuria Mahmed , Muhammad Mahyiddin Ramli , Mohd Arif Anuar Mohd Salleh , Mohd Fairul Sharin Abdul Razak , Ayu Wazira Azhari , Chobpattana V. , Kaczmarek L.

In this study, a sol gel procedure for preparation of TiO2 thin films with graphene oxide (GO) was developed. The effect of PEG and SDS addition on the microstructure of the films as well as the photocatalytic activity of the thin film was also investigated. The morphology and surface structure of the films were studied by SEM and AFM while the photocatalytic activity of the films was analyzed by measuring the degradation of methylene blue under sunlight irradiation using UV-Vis spectrophotometer. It was found that GO/TiO2 thin film with PEG shows a smaller and porous particle while GO/TiO2 thin film with SDS formed a very smooth surface and very fine particles. Therefore, in AFM analysis reveals that surface roughness decreases with the addition of PEG and SDS. Finally, the photocatalytic activity showed that GO/TiO2 thin film with SDS have the most effective self-cleaning property which degrade 64% of methylene blue that act as model of contaminants.