Ku Syahidah Ku Ismail
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Ku Syahidah Ku Ismail
Official Name
Ku Ismail, Ku Syahidah
Alternative Name
Ku Ismail, Ku Syahidah
Ismail, K. S.Ku
Ismail, K. S.K.
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Scopus Author ID
8932508300
Researcher ID
AAA-2532-2019

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  • Publication
    Effect of microwave-assisted COâ‚‚ pyrolysis on the production of activated carbon from confiscated cigarettes
    ( 2023-07)
    Lee Jian Wei
    ;
    Ku Syahidah Ku Ismail
    ;
    Mohamad Firdaus Mohamad Yusop
    ;
    Mohd Azmier Ahmad
    Confiscated cigarettes are a significant problem worldwide, and in Malaysia, the Royal Malaysian Customs Department (RMCD) Perlis had confiscated 1.5 billion sticks of cigarettes from 2016 to 2019 and the cost of disposal reached RM1.2 billion. Confiscated cigarettes are commonly disposed by incineration which can cause environmental pollution. In this study, the cigarette tobacco was converted into activated carbon (AC) via microwave-assisted CO₂ pyrolysis. The tobacco was first carbonized at 300℃, followed by carbon dioxide (CO₂) activation under microwave heating. The highest yield, 31% was obtained at 616W for 6 min. The BET surface area for tobacco, char and the best AC produced were 1.99, 1.21 and 1.69 m2/g, respectively. Response surface methodology (RSM) of dye removal from AC showed that the optimum condition with the best adsorption properties was achieved at 364 Watt for 2 minutes, which resulted in 87.4% removal of methylene blue (MB). Due to the low surface area, the capability of the AC to adsorb MB dye might be assisted by a diversified factors that contributes to the adsorption mechanism. Modelling of the adsorption data also showed that the adsorption process occurs in multilayers of the adsorbent, best fit to the Freundlich isotherm. Microwaveassisted CO₂ pyrolysis shows potential in the production of AC from tobacco and could be further improved to increase the surface area.
  • Publication
    Effect of molasses-based wastewater irrigation on the rice yield and heavy metals uptake by Oryza sativa: a field study
    (AIP Publishing Ltd., 2023)
    Nuratikah Ghazali
    ;
    Ku Syahidah Ku Ismail
    ;
    Roslaili Abd Aziz
    ;
    Nyvee Inthano
    ;
    Ahmad Radi Wan Yaakub
    ;
    Md Nabil Ab Adzim Saifuddin
    ;
    Ng Hock Hoo
    ;
    Ayob Katimon
    The molasses-based effluent discharge contains significant amount of nutrients (e.g. Fe, Mg, K), which has potential use as an organic fertilizer to fit into the waste-to-wealth plan. Apart from that, the presence of toxic heavy metals content should not be underestimated as it could somehow end up in the rice grains and into the food chains. Thus, in this present work, the concentrations of Al, Cr, Cu and Ni in paddy crops from three different plots irrigated with the molasses-based effluent from an ethanol distillery; Control Plot, Plot 1 (repeatedly irrigated) and Plot 2 (irrigated for the first time) were investigated. All the heavy metals were found to be within the limits indicated by the Food and Agriculture Organization (FAO) for the reuse of wastewater for cultivation, Standard B in the Fifth Schedule, Environmental Quality (Industrial Effluent) Regulations 2009, and the Malaysia Ground Water Quality Standard (MGWQS) for Agricultural 2019 by the Department of Environment Malaysia. The results postulated that the rice yield in Plot 2 was higher compared to the other plots. The study also revealed that the concentrations of the heavy metals in the paddy plants decreased when mobilized from the roots to the rice grains for all sampling plots (p < 0.05). The bioconcentration factor (BCF) for Cu and Ni showed the highest values of 2.01 and 4.89, respectively in Plot 1. As the heavy metals concentration in wastewater were within the allowed limit, metals present in the paddy plant parts could be mobilized from the metals readily present in the soil. These results indicated that the molasses-based distillery’s effluent could be a source of plant nutrients as the rice yields improved and have potential to be used for paddy irrigation, as long as it is contained from leaching into water reservoirs.xc
  • Publication
    Effect of Microwave-Assisted COâ‚‚ Pyrolysis on the production of activated carbon from confiscated cigarettes
    ( 2023-07)
    Lee Jian Wei
    ;
    Ku Syahidah Ku Ismail
    ;
    Mohamad Firdaus Mohamad Yusop
    ;
    Mohd Azmier Ahmad
    Confiscated cigarettes are a significant problem worldwide, and in Malaysia, the Royal Malaysian Customs Department (RMCD) Perlis had confiscated 1.5 billion sticks of cigarettes from 2016 to 2019 and the cost of disposal reached RM1.2 billion. Confiscated cigarettes are commonly disposed by incineration which can cause environmental pollution. In this study, the cigarette tobacco was converted into activated carbon (AC) via microwave-assisted CO₂ pyrolysis. The tobacco was first carbonized at 300°C, followed by carbon dioxide (CO₂) activation under microwave heating. The highest yield, 31% was obtained at 616W for 6 min. The BET surface area for tobacco, char and the best AC produced were 1.99, 1.21 and 1.69 m2/g, respectively. Response surface methodology (RSM) of dye removal from AC showed that the optimum condition with the best adsorption properties was achieved at 364 Watt for 2 minutes, which resulted in 87.4% removal of methylene blue (MB). Due to the low surface area, the capability of the AC to adsorb MB dye might be assisted by a diversified factors that contributes to the adsorption mechanism. Modelling of the adsorption data also showed that the adsorption process occurs in multilayers of the adsorbent, best fit to the Freundlich isotherm. Microwave-assisted CO2pyrolysis shows potential in the production of AC from tobacco and could be further improved to increase the surface area.
      10  11
  • Publication
    Pretreatment of Leucaena Leucocephala Using Deep Eutectic Solvent for Ethanol Production by Kluyveromyces Marxianus UniMAP 1–1
    ( 2023-01-01)
    Ishak M.Z.
    ;
    Khadijah Hanim Abdul Rahman
    ;
    Ahmad Anas Nagoor Gunny
    ;
    Younesi H.
    ;
    Ku Syahidah Ku Ismail
    Conventional pretreatment methods such as alkaline and acid pretreatment which were used in biorefineries to dissolve lignin and hemicellulose faces many drawbacks. These pretreatment methods were considered as toxic not only to the environment, but also to the biomass as further treatment using these solvents will lead to the production of hydroxymethyl furfural (HMF) and furfural, which can inhibit the production of ethanol. Recently, deep eutectic solvents (DES) have grown in popularity as an alternative solvent to substitute conventional pretreatment solvents. DES have a great number of advantages such as biodegradability, non-toxic, low volatility and low cost. Furthermore, DES also is a powerful solvent to dissolve lignin, thus this makes DES a superior solvent to be used in biorefineries compared to alkaline and acid pretreatment. In this study, Leucaena leucocephala seeds and pods were treated with choline chloride – glycerol (ChCl – Gly) based DES at 1:2 molar ratio, and the performance subjected to sugar released and ethanol production were analyzed using high performance liquid chromatography (HPLC). The values were then compared with the conventional pretreatment methods as the controls. The results suggested that DES pretreatment released slightly higher total sugar, 29.28 g/L compared to alkaline and acidic pretreatment at 28.77 and 24.94 g/L, respectively. On the other hand, the yield of ethanol after fermentation in DES treatment were among the highest, which was 0.287 g ethanol/g glucose with 56.27% conversion compared to theoretical yield. The purpose of this report is to offer further information in the interest of making DES as a good replacement for the conventional pretreatment method.
      1  13