Now showing 1 - 2 of 2
  • Publication
    Flexural properties of thin fly ash geopolymers at elevated temperature
    ( 2021)
    Yong-Sing Ng
    ;
    ; ; ;
    Hui-Teng Ng
    ;
    Lynette Wei Ling Chan
    This paper reports on the flexural properties of thin fly ash geopolymers exposed to elevated temperature. The thin fly ash geopolymers (dimension = 160 mm × 40 mm × 10 mm) were synthesised using12M NaOH solution mixed with designed solidsto-liquids ratio of 1:2.5 and Na2SiO3/NaOH ratio of 1:4 and underwent heat treatment at different elevated temperature (300°C, 600°C, 900°C and 1150°C) after 28 days of curing. Flexural strength test was accessed to compare the flexural properties while X-Ray Diffraction (XRD) analysis was performed to determine the phase transformation of thin geopolymers at elevated temperature. Results showed that application of heat treatment boosted the flexural properties of thin fly ash geopolymers as the flexural strength increased from 6.5 MPa (room temperature) to 16.2 MPa (1150°C). XRD results showed that the presence of crystalline phases of albite and nepheline contributed to the increment in flexural strength.
  • Publication
    Evaluation of flexural properties and characterisation of 10-mm thin geopolymer based on fly ash and ladle furnace slag
    ( 2021)
    Ng Yong-Sing
    ;
    ; ; ;
    Lynette Wei Ling Chan
    ;
    Ng Hui-Teng
    ;
    Ong Shee-Ween
    ;
    Ooi Wan-En
    ;
    Hang Yong-Jie
    The formulation and flexural properties of thin fly ash geopolymers with thickness of merely 10 mm and replacement of ladle furnace slag to fly ash in thin geopolymer were presented. The formulation was discussed in terms of NaOH molarity, solid aluminosilicates-to-liquid alkali activator (S/L) mass ratio, and alkali activator (Na2SiO3/NaOH) mass ratio. Thin fly ash geopolymers with flexural strength and Young's modulus of 6.2 MPa and 0.14 GPa, respectively, were obtained by using 12 M NaOH, S/L ratio of 2.5 and Na2SiO3/NaOH ratio of 4.0. A high Na2SiO3/NaOH ratio was implemented for thin geopolymer synthesis to produce a more viscous slurry which helped to retain the shape of a thin geopolymer. The incorporation of ladle furnace slag up to 40 wt.% reported an increment of 26% in flexural strength up to 7.8 MPa as compared to pure fly ash geopolymers and the stiffness was increased to 0.19 GPa. Denser microstructure with improved compactness was observed as the ladle furnace slag acted as the filler. New crystalline phases of calcium silicate hydrate (C–S–H) were formed and coexisted with the geopolymer matrix, which consequently enhanced the flexural strength of thin fly ash geopolymer. This proved that the ladle furnace slag has the potential to be utilised in geopolymer synthesis and will enhance the flexural properties of thin geopolymers. The flexural performance of thin geopolymers in this study was considerably good as the thin geopolymers exhibited comparatively similar flexural strengths, but a higher strength/thickness ratio as compared to geopolymers with thickness greater than 40 mm.
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