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Azduwin Khasri
Preferred name
Azduwin Khasri
Official Name
Azduwin, Khasri
Alternative Name
Khasri, Azduwin
Azduwin, Y. K.
Main Affiliation
Scopus Author ID
55993350600
Researcher ID
K-8421-2019
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1 - 3 of 3
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PublicationAdsorption of basic green 4 onto gasified Glyricidia sepium woodchip based activated carbon: optimization, characterization, batch and column study(Scientific Scholar, 2020)
;Azam Taufik Mohd Din ;Nasehir Khan EM YahayaMohd Azmier AhmadThe abundance of gasification char residues which contributed to solid waste management problem is one of the major concerns in biomass gasification industry. This study focuses on synthesizing gasified Glyricidia sepium woodchip based activated carbon (GGSWAC) for the removal of basic green 4 (BG4) dye, evaluating the GGSWAC physicochemical properties and assessing the BG4 adsorption performance in batch and fixed-bed column systems. The optimal conditions of GGSWAC synthesis were at radiation power, time, and impregnation ratio (IR) of 616 W, 1 min and 1.93 g/g, respectively. The surface area (SBET) and total pore volume (TPV) of GGSWAC were 633.30 m2/g and 0.34 cm3/g, respectively. The Fritz–Schlünder best fitted to the experimental data at all temperatures in the isothermal studies, indicating a monolayer adsorption. The kinetic study showed that BG4 adsorption followed Avrami kinetic model. Based on thermodynamic parameters, the adsorption of BG4 dye onto GGSWAC was an endothermic and spontaneous process. In continuous operation, the Thomas and Yoon–Nelson models successfully predicted BG4 adsorption onto GGSWAC. The low production cost of 0.54 USD/kg showed that GGSWAC is economically feasible for commercialization. -
PublicationValorization of face mask waste as an adsorbent for cationic dye adsorptionThe increasing environmental pollution caused by the disposal of untreated dye-containing effluent and face mask wastes in landfills has become a significant concern. To address this issue, this work focuses on the utilization of face mask wastes as alternative adsorbents for the adsorption of malachite green (MG) dye. These adsorbents offer advantages such as ease of operation, cost-effectiveness, high efficiency, and ready availability. In this study, the raw face mask wastes (RFM) undergo a thermal treatment process in a furnace at 800°C for 21 h before conducting the adsorption tests. The Fourier-transform infrared spectroscopy analysis revealed the presence of various functional groups, including alkane, alkene, alcohol, and carbonyl, in both the treated face mask adsorbent (TFMA) and RFM. The scanning electron microscopy with energy-dispersive X-ray spectroscopy analysis displayed the surface morphologies of RFM as a porous and homogeneous carbon sorbent structure, while TFMA exhibited a heterogeneous and flaky structure. Energy-dispersive X-ray spectroscopy analysis indicated that RFM primarily consisted of carbon elements, followed by oxygen and calcium elements, whereas TFMA predominantly comprised calcium and oxygen elements with a limited amount of carbon. The adsorption experiments, considering various parameters such as initial dye concentration (1,000–1,200 mg/L) and contact time (5–1,500 min), demonstrated that increasing the contact time and initial concentration led to an enhanced adsorption capacity. The maximum adsorption capacity of 2,127 mg/g confirmed the effectiveness of TFMA as an adsorbent for MG. Thermodynamic analysis revealed that the adsorption process was spontaneous and endothermic. The isotherm and kinetic studies showed a good fit between the adsorption data and the Brunauer–Emmett–Teller and pseudo-second-order models as evidenced by high R2 values and low error function values, suggesting a heterogenous adsorption of MG on TFMA.
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PublicationGasification char adsorbent for dye removal: characterization, isotherm, kinetics and thermodynamic studies( 2024)
;Valarmathi SaravananMohd Azmier Ahmad11 1