Alina Rahayu Mohamed
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Preferred name
Alina Rahayu Mohamed
Official Name
Alina Rahayu, Mohamed
Alternative Name
Rahayu, M. Alina
Mohamed, Alina Rahayu
Rahayu Mohamed, Alina
Main Affiliation
Scopus Author ID
55349453800
Researcher ID
DHI-6721-2022

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Synthesis of ultrasonicated amine-functionalized MgO-deposited empty fruit bunch (EFB)-derived biochar for CO2 adsorption

2024-01-01 , Shafawi A.N. , Mohd Amer N. , Aghamiri A.R. , Lahijani P. , Mohammadi M. , Alina Rahayu Mohamed

In this study, biochar derived from empty fruit bunch (EFB) was modified by sonication, amine functionalization, and MgO deposition to increase CO2 uptake capacity towards addressing the global warming problem. The optimal conditions for amine functionalization were a biochar to melamine mass ratio of 5:2, an activation temperature of 700 °C, and a heating rate of 15 °C/min. The sequential sonication, amine functionalization, and MgO deposition resulted in the ultrasonicated amine-functionalized MgO-deposited biochar (UAMB) with the highest CO2 uptake capacity of 84.95 mg/g, which is a 142% increase compared to the pristine biochar (35.10 mg/g). The results of XRD, SEM–EDX, FTIR, Raman, BET, Boehm titration, and XPS analysis showed that the sequential treatments improved the porosity, surface area, and surface chemistry of the modified biochar due to the presence of MgO, pyridine, pyrrole, and nitrile, resulting in a superior increase in CO2 uptake capacity. Advantageously, this modified biochar exhibited the highest affinity for CO2 compared to air, methane, and nitrogen and was stable up to 12 cycles of CO2 adsorption–desorption. Kinetic studies showed that the Avrami kinetic model best described CO2 adsorption on the biochar, with physisorption being the main adsorption mechanism and chemisorption making only a minor contribution to CO2 adsorption. CO2 capture tests in a fixed-bed adsorption system showed that the best adsorption conditions were at a gas flow rate of 30 mL/min, an initial CO2 concentration of 15%, and an adsorption temperature of 30 °C. The excellent performance of this modified biochar is promising for efficient CO2 capture to reduce CO2 emissions.

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Production of Solid Biofuels From Renewable Resources: A Review

2023-06-09 , Ras Izzati Ismail , Khor Chu Yee , Shaari A.R. , Alina Rahayu Mohamed , Abdul Halim M.H.B. , Rahman A.A.A. , Lee Yit Leng , Nur Lailina Makhtar , Norawanis Abdul Razak

Increasing concerns over greenhouse gas emissions, volatile fossil fuel prices, and political instability have led to biomass as a renewable energy source. Close cooperation from the government supported by independent bodies also helps produce this effective and sustainable energy source. As a result, the current growth of solid biofuels has increased tremendously. Agricultural, municipal, forest, commercial waste and dedicated energy crops are the main sources of biomass. Due to this biomass's nature, the methods to produce them into solid biofuels are also different. The energy potential of these biomass sources is quite dependent on the use of technology and public awareness. Therefore, this paper review feedstock biomass, processing processes, product types and properties of solid biofuels in terms of mechanical and combustion. The paper also reviews the solid biofuel production situation in Malaysia.

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The Effect of Different Waste Material Binders in Relation to Khaya Senegalensis Solid Fuel Pellet Quality

2023-11-01 , Ras Izzati Ismail , Khor Chu Yee , Alina Rahayu Mohamed , Mustafa N.M.K.N. , Lee Yit Leng , Nur Lailina Makhtar , Norawanis Abdul Razak

Fuel pellets are an attractive renewable energy source derived from biomass sources thanks to their uniformity and ease of handling. However, raw biomass and waste material binders have several drawbacks, which include poor physical properties, particularly low density and compositional heterogeneity, which restrict their wider use as a general source of energy. Besides, due to the low energy density, low bulk density, and uneven shape and size of raw biomass, it is very difficult to store and transport biomass in its original form, which decreases transport efficiency. This study investigated the effect of waste material binders (rice husk, corn cob, and sugarcane bagasse) on the mechanical and thermal properties of Khaya Senagalensis pellets. The mechanical and thermal properties were determined according to ASTM standards. Waste material binders have affected pellet quality such as density, bulk density, moisture content, durability, compressive strength, shatter index, water resistance, ash content, volatile matter, fixed carbon, and calorific value. From the analysis, sugarcane bagasse as a binder shows the highest quality pellet in terms of mechanical properties. Sugarcane bagasse produces the highest density (0.967g/cm3), bulk density (0.4094), durability (99.71%), shatter index (98.85%), water resistance (98.35%), and thermal properties, which are the highest volatile matter (94.71%) and the lowest ash content (1.71%). In a nutshell, sugarcane bagasse is a good binder that gives a positive impact to the K.senegalensis pellets in terms of storage and transportation compared to corn cob and rice husk binder.

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Inhibition of Aspergillus flavus by Momordica charantia Ethanolic Leaves Extract for Mushroom Protection

2023 , Noor Hasyierah Mohd Salleh , Zulkarnay Zakaria , Norhidayah Abd Aziz , Munusamy T. , Alina Rahayu Mohamed , Ahmad Anas Nagoor Gunny

Pleurotus ostreatus, better known as oyster mushroom is one of the world’s widely cultivated mushroom. Infection from pathogenic fungi is one of the major reasons causing losses of mushroom during cultivation. The objective of this study is to investigate the antifungal property of Momordica charantia leaves extract against Aspergillus flavus for mushroom protection. The inhibitory effect of M. charantia leaves extract against A. flavus isolated from infected P. ostreatus mushroom bag was investigated using pour plate technique. Inhibition of A. flavus mycelial growth was the highest at extract concentration of 9.64 v/v %, temperature 26℃ and incubation time of 96 hours with inhibitory value of 70.58 ± 0.00 %, 78.4 ± 0.00 % and 63.33 ± 2.89 % respectively. Structural morphology of the mycelia grown on the treated plate also showed morphological alteration compared to the control plate. Hence, Momordica charantia leaves extract may serves as a promising fungicides alternative to chemical use for controlling invasion of A. flavus on oyster mushroom.

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Mechanical and physical properties of khaya senegalensis solid fuel pellet with different binder percentages

2021-10-25 , Ras Izzati Ismail , Shaari A.R. , Khor Chu Yee , Alina Rahayu Mohamed , Rahim M.S.b.A. , Lee Yit Leng , Wan Nur A'tiqah Wan Draman , Nur Lailina Makhtar , Norawanis Abdul Razak , Mohd Riduan Jamalludin

The characteristics of the solid fuel pellets, such as its strength, durability and density can be used to assess its quality. During the transport and storage, pellets with low strength and durability produces dusts and ultimately resulting in equipment blockage, high pollution emissions, and an increased risk of fire and explosion. Therefore, pellet manufacturing process should be given priority to improve pellet quality. The use of binder in the production of pellets will aid in improving pellet quality. Therefore, this study investigates the influence of different binder percentages on the mechanical properties of K. senegelensis fuel pellets. Durability, unit density, bulk density and diametral compressive strength testing were carried out in compliance with international standards. It was discovered that pellets containing 4% cassava starch binder produces better results, particularly in terms of durability and compressive ldiametral strength.

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