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Influence of Amaranth dye concentration on the efficiency of hybrid system of photocatalytic fuel cell and Fenton process

2017-10-01 , Noradiba Nordin , Ho Li Ngee , Ong Soon An , Abdul Haqi Ibrahim , Wong Yee Shian , Sin Li Lee , Oon Yoong Sin , Oon Yoong Ling

A novel sustainable hybrid system of photocatalytic fuel cell (PFC) and Fenton process is an alternative wastewater treatment technology for energy-saving and efficient treatment of organic pollutants. The electrons generated from PFC photoanode are used to produce H2O2 in the Fenton reactor and react with the in situ generation of Fe2+ from sacrificial iron for hydroxyl radical formation. In this study, the effect of different initial Amaranth dye concentrations on degradation and electricity generation were investigated. ZnO/Zn photoanode was prepared by anodizing method and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Results revealed that the maximum power density (9.53 mW/m2) and current density (0.0178 mA/m2) were achieved at 10 mg/L of Amaranth. The correlation between dye degradation, voltage output, and kinetic photocatalytic degradation were also investigated and discussed.

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Hybrid system of photocatalytic fuel cell and Fenton process for electricity generation and degradation of Reactive Black 5

2017-01-01 , Noradiba Nordin , Ho Li Ngee , Ong Soon An , Abdul Haqi Ibrahim , Wong Yee Shian , Lee Sin Li , Oon Yoong Sin , Oon Yoong Ling

A novel hybrid system composed of a photocatalytic fuel cell (PFC) and Fenton reactor was developed with the aim to degrade the azo dye Reactive Black 5 (RB5) and generate electricity. Compared to previously established system of bioelectro-Fenton system, microbial fuel cell (MFC) system has significant challenge in the development and operation system. Therefore, PFC is used instead of MFC to generate electrons for the Fenton system. The effect of azo dye (RB5) on each PFC and Fenton reactor was investigated. The experimental results showed that maximum power output was achieved in the absence of dye in the Fenton reactor of this hybrid system. Furthermore, higher degradation efficiency of RB5 could also be observed in the PFC reactor in this hybrid system.