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The Effects of Self-Polymerized Polydopamine Coating on Mechanical Properties of Polylactic Acid (PLA)–Kenaf Fiber (KF) in Fused Deposition Modeling (FDM)

2023-06-01 , Sanusi Hamat , Syamir Alihan Showkat Ali , Salit M.S. , Yidris N. , Showkat Ali S.A. , Mohd Sabri Hussin , Muhamad Saifuldin Abdul Manan , Muhamad Qauyum Zawawi Ahamad Suffin , Maliki Ibrahim , Ahmad Nabil Mohd Khalil

This research examines the impact of self-polymerized polydopamine (PDA) coating on the mechanical properties and microstructural behavior of polylactic acid (PLA)/kenaf fiber (KF) composites in fused deposition modeling (FDM). A biodegradable FDM model of natural fiber-reinforced composite (NFRC) filaments, coated with dopamine and reinforced with 5 to 20 wt.% bast kenaf fibers, was developed for 3D printing applications. Tensile, compression, and flexural test specimens were 3D printed, and the influence of kenaf fiber content on their mechanical properties was assessed. A comprehensive characterization of the blended pellets and printed composite materials was performed, encompassing chemical, physical, and microscopic analyses. The results demonstrate that the self-polymerized polydopamine coating acted as a coupling agent, enhancing the interfacial adhesion between kenaf fibers and the PLA matrix and leading to improved mechanical properties. An increase in density and porosity was observed in the FDM specimens of the PLA–PDA–KF composites, proportional to their kenaf fiber content. The enhanced bonding between kenaf fiber particles and the PLA matrix contributed to an increase of up to 13.4% for tensile and 15.3% for flexural in the Young’s modulus of PLA–PDA–KF composites and an increase of up to 30% in compressive stress. The incorporation of polydopamine as a coupling agent in the FDM filament composite led to an improvement in tensile, compressive, and flexural stresses and strain at break, surpassing that of pure PLA, while the reinforcement provided by kenaf fibers was enhanced more by delayed crack growth, resulting in a higher strain at break. The self-polymerized polydopamine coatings exhibit remarkable mechanical properties, suggesting their potential as a sustainable material for diverse applications in FDM.

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Effect of kenaf fiber loading on the tensile properties of 3D printing PLA filament

2023-01-01 , Lau H.Y. , Mohd Sabri Hussin , Sanusi Hamat , Muhamad Saifuldin Abdul Manan , Ibrahim M. , Hafizawati Zakaria

As know Polylactic acid (PLA) is a popular and widely used thermoplastic material used in fused filament fabrication (FDM) due to its biodegradability and biocompatibility. As PLA was identified as a brittle material, reinforcement was used to enhance the properties of the PLA. This paper aims to study the effect of using various kenaf volume ratios on the tensile properties of the 2003D PLA filament for 3D printing. The study began by extruding 2003D grade PLA pellet from Ingeo NatureWorks into a single filament extruder machine with an extrusion temperature of 190 °C and a screw rate of 7 rpm. The 90° raster angle of line infill pattern with 100 % infill density were used for the 3D printing specimens. Mechanical test standards such as ASTM D638, was used for tensile testing to analyse the quality of the extruded PLA single filament. As result, the with kenaf fibre loading of 15 % shows the optimum tensile properties among the filler loading, hence it is proven that the tensile properties of the was indeed being enhanced by the additional of the kenaf fibre as reinforcement.

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Tensile Properties of 3D Printed Recycled PLA Filament: A Detailed Study on Filament Fabrication Parameters

2023-10-01 , Sanusi Hamat , Ishak M.R. , Salit M.S. , Yidris N. , Syamir Alihan Showkat Ali , Mohd Sabri Hussin , Maliki Ibrahim , Asmawi Sanuddin

Polylactic acid (PLA), a biodegradable and biocompatible thermoplastic commonly utilized in 3D Printing filaments, undergoes changes in properties upon recycling. The objective was to elucidate the role of extrusion temperature and screw speed in modulating the quality of recycled PLA filament, as well as in controlling its dimensional attributes. Recycled PLA pellets (3D850D) were extruded using a single filament extruder machine within an extrusion temperature range of 145°C to 165°C and a screw speed varying from 2 rpm to 6 rpm. The extruded filaments were subsequently 3D printed into specimens adopting a 0° raster angle, line infill pattern, and a 100 percent infill density, then tested as per ASTM D638 mechanical standards. The study revealed a profound influence of extrusion parameters on the filament's ultimate tensile strength, yield strength, and diameter. Optimal extrusion conditions-155°C and 5 rpm-resulted in maximum mechanical strengths, while the parameters yielding filament diameters closest to commercial standards were identified as 5 rpm and 155°C. These results under-score the possibility of optimizing the recycled PLA filament's properties through adept control of extrusion parameters. Consequently, this investigation supports the potential use of recycled PLA filament in the 3D printing industry as a sustainable and performance-efficient material, offering a tangible step towards environmentally friendly additive manufacturing practices.