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The Suitability of Photocatalyst Precursor Materials in Geopolymer Coating Applications: A Review

2022-09-01 , Liyana Jamaludin , Rafiza Abd Razak , Mohd. Mustafa Al Bakri Abdullah , Vizureanu P. , Bras A. , Imjai T. , Sandu A.V. , Shayfull Zamree Abd. Rahim , Heah Cheng Yong

Today, the building and construction sector demands environmentally friendly and sustainable protective coatings using inorganic coating materials for safe, non-hazardous, and great performance. Many researchers have been working on sustainable solutions to protect concrete and metal infrastructures against corrosion and surface deterioration with the intention of introducing green alternatives to conventional coatings. This article presents a review of developments of geopolymer pastes doped with different types of photocatalyst precursors including factors affecting geopolymer properties for enhancing coating with photocatalytic performance. Photodegradation using geopolymer photocatalyst has great potential for resolving harmless substances and removing pollutants when energized with ultraviolet (UV) light. Although geopolymer is a potentially new material with great properties, there has been less research focusing on the development of this coating. This study demonstrated that geopolymer binders are ideal precursor support materials for the synthesis of photocatalytic materials, with a significant potential for optimizing their distinctive properties.

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Mechanical Performance, Microstructure, and Porosity Evolution of Fly Ash Geopolymer after Ten Years of Curing Age

2023-02-01 , Aziz I.H.A. , Mohd. Mustafa Al Bakri Abdullah , Rafiza Abd Razak , Zarina Yahya , Mohd Arif Anuar Mohd Salleh , Chaiprapa J. , Rojviriya C. , Vizureanu P. , Sandu A.V. , Muhammad Faheem Mohd. Tahir , Alida Abdullah , Liyana Jamaludin

This paper elucidates the mechanical performance, microstructure, and porosity evolution of fly ash geopolymer after 10 years of curing age. Given their wide range of applications, understanding the microstructure of geopolymers is critical for their long-term use. The outcome of fly ash geopolymer on mechanical performance and microstructural characteristics was compared between 28 days of curing (FA28D) and after 10 years of curing age (FA10Y) at similar mixing designs. The results of this work reveal that the FA10Y has a beneficial effect on strength development and denser microstructure compared to FA28D. The total porosity of FA10Y was also lower than FA28D due to the anorthite formation resulting in the compacted matrix. After 10 years of curing age, the 3D pore distribution showed a considerable decrease in the range of 5–30 µm with the formation of isolated and intergranular holes.