Now showing 1 - 5 of 5
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Review—Bibliometrics and current research trends on direct carbon-solid oxide fuel cells utilizing biomass as fuel

2023 , Michelle S. Carbonell , Al Rey C. Villagracia , Ong Hui Lin , Ruey-An Doong

Biomass is considered a viable alternative source of energy after thermochemical conversion techniques and activation methods are adopted for its conversion to biochar and activated carbon, respectively. This work provides the bibliometrics and recent developments on DC-SOFC using biochar as fuel and is further enhanced through the carbon activation method. This study reported the dominant researchers from different countries and their contributions to the development of DC-SOFC. This study provided an overview of the physicochemical characteristics of the biochar and its corresponding effect in the operation of a DC-SOFC in terms of the electrochemical performance when used as fuel. Data reveal that other biomasses can still be pyrolyzed and used as DC-SOFC fuel. This paper includes that among the alternative carbon fuels to date, pomelo peel char has the most efficient and effective biochar fuel for DC-SOFC, which yields the best output in terms of parameters such as peak power density and fuel utilization rate. The activation method, as applied in biochar fuel, is an effective way to enhance the performance of the fuel cell. Prospects and challenges addressing identified gaps for DC-SOFC with high power output operated with biomass as fuel are similarly discussed.

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First principles investigation on the nitrogen-doped planar aluminene for hydrogen storage application

2020 , G R Pedrosa , A R Villagracia , D S Bayasen , Ong Hui Lin , David M. , N Arboleda , H., Lin.

With the rise of carbon emission daily, a pursuit for cleaner energy such as hydrogen fuel is necessary. Obtaining a good hydrogen storage is one of the main bottleneck to achieve a working hydrogen economy. Materials including two-dimensional systems have been widely investigated for potential hydrogen storage. In this work, the effects of nitrogen on the hydrogen adsorption on planar hexagonal aluminene was studied using density functional theory. Aluminene was decorated with nitrogen at different sites: top, hollow and bridge. Results showed that nitrogen was adsorbed at the top, bridge and hollow sites at a distance of 0.00Ã… to 1.80 Ã… with binding energies of 2.71 eV, 4.88 eV, and 3.44 eV, respectively. Comparing to the pristine aluminene, there was no major difference with its electronic and magnetic properties based on the density of states of the nitrogen-doped aluminene while the nitrogen atom gained some charges from the aluminium atoms based on the charge difference. On the other hand, a hydrogen molecule was adsorbed with binding energies ranging from 13.4meV to 26.3 meV close enough to the adatom on the decorated system. Minimal broadening of energy level was found from the density of states. This work shows that aluminene with nitrogen impurity can adsorb hydrogen molecules. However, high concentration of nitrogen will lower the hydrogen capacity of aluminene.

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Green synthesis and characterization of Graphene quantum dots from key lime juice

2023 , Nur Atirah Afifah Sezali , Siew Suan Ng , Ong Hui Lin , Al Rey Villagracia , Mohd Hanif Mohd Pisal , Ruey-An Doong

Graphene quantum dots (GQDs) are one of the members of graphene family with unique properties such as quantum confinement effect, photoluminescence effect, and strong conductivity. This work prepared the GQDs using lime juice obtained from the waste of locally grown key limes as the precursor. The hydrothermal method was used in the preparation of the GQDs. The fluorescence effect of the GQDs was observed under a UV lamp irradiation while other characterization was conducted using high-resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), X-ray powder diffraction (XRD), and Raman spectroscopy. The GQD preparation was successful with the emission of a strong blue color when the GQD was put under a 365 nm UV light irradiation. It was found that the particle size of the prepared GQDs was in the range of 0.7–2.8 nm with an average diameter of 1.3 ± 0.5 nm. The characterization results proved the formation of GQDs as one of the graphene nanomaterials.

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Hydrogen adsorption on calcium-decorated planar aluminene using density functional theory

2020 , D S Bayasen , A R Villagracia , G R Pedrosa , Lin H. , Ong Hui Lin , David M. , N Arboleda

With the rising demand for clean energy, the concept of hydrogen economy has grown more popular, and with this popularity the need for better hydrogen storage materials increases. Decorated surface materials such as planar hexagonal aluminene are being studied to determine their potential as good hydrogen storage materials. This study theoretically investigates hydrogen adsorption on aluminene decorated with calcium, where calcium is binded on the top, bridge and hollow sites of aluminene using density functional theory. Results on decoration adsorption have shown that calcium can easily bind a distance of 1.80 Ã… to 2.80 Ã… on the top, bridge and hollow sites with binding energies of 1.85 eV, 2.01 eV, and 3.32 eV, respectively. The density of states of the calcium-decorated surface show that its electronic property is generally maintained with zero magnetization. Small amount of charges were adsorbed from the aluminium atoms to the calcium atom based on the charge difference. This leads to hydrogen molecule adsorption with low adsorption energies ranging from 34.13 meV to 80.51 meV. In addition, minimal broadening of energy levels were shown by the density of states. With these results, it can be concluded that planar hexagonal aluminene with low concentration of calcium atoms may lower the hydrogen capacity of aluminene.

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Revealing the water resistance, thermal and biodegradation properties of Citrus aurantifolia crosslinked Tapioca Starch/Nanocellulose bionanocomposites

2020 , Ong Hui Lin , Al Rey Villagracia , Wei Tieng Owi , Sam Sung Ting , Hazizan Md Akil

Moisture absorption, thermal and biodegradation properties of nanocellulose (NC) reinforced bionanocomposite tapioca starch (TS) films crosslinked with Citrus aurantifolia or lime juice (LJ) were investigated for food packaging applications. The films were synthesized by solvent casting using different amounts of nanocellulose and crosslinkers: lime juice and a commercial citric acid (CA). Nanocellulose as reinforcing filler was obtained from oil palm empty fruit bunches through acid hydrolysis. Crystallinity of all TS bionanocomposites was determined using X-ray diffractometry. TS bionanocomposites interaction with water was studied by means of moisture absorption, moisture content and swelling. Flory-Huggin model was used to measure the crosslinked density of crosslinked TS bionanocomposites which indicated successful crosslinking using LJ and CA for TS. The crystallinity of TS film increased from 43.5% for neat TS to 51.6% for TS film with inclusion of NC. LJ-crosslinked TS film with 1 wt% of NC (based on starch content) had the lowest moisture absorption and swelling ratio. TS bionanocomposites with LJ had better thermal and biodegradation properties compared to commercial CA-crosslinked TS biocomposites, which can be a potential food packaging material among the tested bionanocomposites.