Now showing 1 - 8 of 8
  • Publication
    Arthropods-mediated Green Synthesis of Zinc Oxide Nanoparticles using Cellar Spider Extract: A Biocompatible Remediation for Environmental Approach
    ( 2024-06-12) ; ;
    Irfan M.A.R.
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    ; ; ;
    Afnan Uda M.N.
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    Huzaifah M.R.M.
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    Ali M.M.
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    Ibrahim N.H.
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    Makhtar M.M.Z.
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    Ng Q.H.
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    ; ; ; ;
    Ruslan M.A.M.
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    This study presents an eco-friendly approach to synthesizing zinc oxide nanoparticles (ZnO NPs) using extracts from cellar spiders, addressing environmental and health concerns associated with conventional methods. The spider extract efficiently reduced zinc acetate dihydrate, and the synthesized ZnO NPs underwent comprehensive quantitative characterization, including size, shape, morphology, surface chemistry, thermal stability, and optical properties using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), zeta potential measurements, thermogravimetric analysis (TGA), and UV-vis spectroscopy. The nanoparticles exhibited intended characteristics, and their adsorption capability for methylene blue (MB) was quantitatively assessed using the Freundlich isotherm model and pseudo-second-order kinetic model, providing numerical insights into MB removal efficiency. The study demonstrates the potential of these green-synthesized ZnO NPs for applications in environmental remediation, wastewater treatment, and antibacterial therapies, contributing to both sustainable nanomaterial development and quantitative understanding of their functional properties.
      3  1
  • Publication
    The Influence of Cement Content to Properties of High Strength Anti Washout Concrete (HSAWC)
    ( 2024-04-19) ;
    Muhammad Haikal Farizad
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    ;
    The high strength of concrete required a lot of cement content to increase its strength but not for the anti washout concrete (AWC) or underwater concrete (UWC). AWC will face another problem which is higher cement content could make the segregation to occur. This segregation process will give bad impact to the strength of the AWC. This research studied on four different cement content to examine: 450 kg/m3, 500 kg/m3, 550 kg/m3 and 600 kg/m3 towards its fresh and hardened properties of concrete. Superplasticizer is used as water reducing agent in the mix proportions to achieve high strength and self-consolidated concrete. Apart from that, there are two types of concrete samples produced, the air sampling concrete and underwater sampling concrete which have the same mix proportion. The overall results show a good correlation between the cement content in the mix and the strength of the air sampling concrete achieved. However, anti washout concrete having issues which is segregation. This segregation had affected the strength of the concrete. In conclusion, Anti washout concrete shows that optimal cement content without any viscocity modifying agent (VMA) is at 550 kg/m3
  • Publication
    Arthropods-mediated green synthesis of Zinc oxide nanoparticles using cellar spider extract a biocompatible remediation for environmental approach
    ( 2024-06) ; ;
    M. A. R. Irfan
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    ; ; ;
    MRM Huzaifah
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    Maimunah Mohd Ali
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    Nur Hulwani Ibrahim
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    Muaz Mohd Zaini Makhtar
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    ; ; ; ; ;
    Mahfuz Affif Mohd Ruslan
    ;
    This study presents an eco-friendly approach to synthesizing zinc oxide nanoparticles (ZnO NPs) using extracts from cellar spiders, addressing environmental and health concerns associated with conventional methods. The spider extract efficiently reduced zinc acetate dihydrate, and the synthesized ZnO NPs underwent comprehensive quantitative characterization, including size, shape, morphology, surface chemistry, thermal stability, and optical properties using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), zeta potential measurements, thermogravimetric analysis (TGA), and UV-vis spectroscopy. The nanoparticles exhibited intended characteristics, and their adsorption capability for methylene blue (MB) was quantitatively assessed using the Freundlich isotherm model and pseudo-second-order kinetic model, providing numerical insights into MB removal efficiency. The study demonstrates the potential of these green-synthesized ZnO NPs for applications in environmental remediation, wastewater treatment, and antibacterial therapies, contributing to both sustainable nanomaterial development and quantitative understanding of their functional properties.
  • Publication
    Setting time and after setting properties of high calcium fly ash geopolymers with different concentration of sodium hydroxide
    ( 2021)
    Rosnita Mohamed
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    ; ;
    Ikmal Hakem Aziz
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    ;
    Noor Fifinatasha Shahedan
    Setting time in geopolymers is known as the time taken for the transition phase of liquid to solid of the geopolymer system in which is represented in the initial setting and final setting. Setting time is significant specifically for application in the construction field. This study intends to determine the setting time of high calcium fly ash geopolymers and the properties of the geopolymers after setting (1-day age). This includes the determination of heat evolved throughout geopolymerization using Differential Scanning Calorimeter. After setting properties determination includes compressive strength and morphology analysis at 1-day age. High calcium fly ash was used as geopolymer precursor. Meanwhile, for mixing design, the alkali activator was a mixture of sodium silicate and sodium hydroxide (concentration varied from 6M-14M) with a ratio of 2.5 and a solid-to-liquid ratio of 2.5. From this study, it was found that high calcium fly ash geopolymer with 12M of NaOH has a reasonable setting time which is suitable for on-site application as well as an optimal heat evolved (–212 J/g) which leads to the highest compressive strength at 1-day age and no formation of microcracks observed on the morphology. Beyond 12M, too much heat evolved in the geopolymer system can cause micro-cracks formation thus lowering the compressive strength at 1-day age.
  • Publication
    Use of Palm Kernel Shell from Agriculture Waste as Partial Replacement for Coarse Aggregate in Hot Mix Asphalt
    Palm kernel shell (PKS) is known as a waste material that produced by oil palm factory. In this research, PKS will be used as an alternative to improve the strength and performance of hot mix asphalt (HMA). The bitumen grade of 60/70 PEN and ACW14 had been used in the research. To investigate the strength of PKS in term of designing wearing course, bitumen content of 4% to 6% and different mix design with different percentages content of PKS were provided. The total specimens prepared in this research are 45 specimens. The specific gravity of PKS was lower and showed the high capacity in water absorption compare to the natural aggregate. The increment of percentage for PKS in HMA make the strength in Marshall Specimen became decreases as stated in the result and discussion. Result of optimum bitumen content for PKS 10, PKS 30 and PKS 50 were 4.72%, 4.86% and 4.90% individually. All optimum bitumen content in this research was satisfied with JKR Standard 2008 in term of the design parameter. The specimen of PKS 10, PKS 30 was classified as heavy traffic and PKS 50 was classified as medium traffic. PKS 10 was shown as a good partial replacement for natural aggregate due to the admissibility of parameter, environmental friendly factor and cheapest in costing.
  • Publication
    Exploring the potential of agricultural waste as natural resource-based adsorbents for methylene blue removal
    ( 2024-01-01) ;
    Muhamad Farid Idham Sulaiman
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    Ain Nihla Kamarudzaman
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    ; ;
    Syakirahafiza Mohammed
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    ;
    Deák G.
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    Excessive agricultural waste in the agricultural industry leads to various forms of pollution, including water pollution. To address this issue, there's a growing interest in finding alternative methods. One approach is to utilize agricultural waste as natural resource-based adsorbents to eliminate contaminants, such as the case of methylene blue (MB) in this study. The study specifically focuses on using rice husk (RH) from a local rice mill in Perlis, Malaysia, to absorb methylene blue. The structure of rice husk, characterized by scanning electron microscopy (SEM), reveals a coarser and more compact outer area, contributing to its absorption capacity for methylene blue. The study on rice husk involves three main aspects: contact time, adsorbent dosage, and dye concentration. The removal percentage of MB increased as the three studied adsorption parameters increased. The adsorption data were analyzed using Langmuir and Freundlich adsorption isotherms, with the the Freundlich Isotherms were found to be more suitable based on higher coefficient of correlation (R2) values compared to Langmuir. The pseudo-second-order kinetics model demonstrated a higher R2value (1.00) compared to the pseudo-first-order model (0.747). The results indicate promising potential for addressing pollution through sustainable means and provide insights into the adsorption process under varying conditions.
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  • Publication
    Influence of Polyformaldehyde Monofilament fiber on the engineering properties of foamed concrete
    ( 2022)
    Md Azree Othuman Mydin
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    Mohd Nasrun Mohd Nawi
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    ; ;
    Madalina Simona Baltatu
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    Andrei Victor Sandu
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    Petrica Vizureanu
    Foamed concrete is considered a green building material, which is porous in nature. As a result, it poses benefits such as being light in self-weight, and also has excellent thermal insulation properties, environmental safeguards, good fire resistance performance, and low cost. Nevertheless, foamed concrete has several disadvantages such as low strength, a large amount of entrained air, poor toughness, and being a brittle material, all of which has restricted its usage in engineering and building construction. Hence, this study intends to assess the potential utilization of polypropylene fibrillated fiber (PFF) in foamed concrete to enhance its engineering properties. A total of 10 mixes of 600 and 1200 kg/m3 densities were produced by the insertion of four varying percentages of PFF (1%, 2%, 3%, and 4%). The properties assessed were splitting tensile, compressive and flexural strengths, workability, porosity, water absorption, and density. Furthermore, the correlations between the properties considered were also evaluated. The outcomes reveal that the foamed concrete mix with 4% PFF attained the highest porosity, with approximately 13.9% and 15.9% for 600 and 1200 kg/m3 densities in comparison to the control specimen. Besides, the mechanical properties (splitting tensile, compressive and flexural strengths) increased steadily with the increase in the PFF percentages up to the optimum level of 3%. Beyond 3%, the strengths reduced significantly due to poor PFF dispersal in the matrix, leading to a balling effect which causes a degraded impact of scattering the stress from the foamed concrete vicinity to another area of the PFF surface. This exploratory investigation will result in a greater comprehension of the possible applications of PFF in LFC. It is crucial to promote the sustainable development and implementation of LFC materials and infrastructures.
      2  3
  • Publication
    Mechanical performance of Fly Ash based Geopolymer (FAG) as road base stabilizer
    ( 2022) ; ;
    Andrei Victor Sandu
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    Thanongsak Imjai
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    Petrica Vizureanu
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    Mohd Rosli Mohd Hasan
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    Mohammad Almadani
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    Ikmal Hakem Ab Aziz
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    This study examines the strength development of fly ash-based geopolymer (FAG) as a stabilizer for road base material for pavement construction. In the last decade, there has been a rapid development of conventionally treated bases, such as cement-treated bases. However, a major problem with this kind of application is the shrinkage cracking in cement-treated bases that may result in the reflection cracks on the asphalt pavement surface. This study explores the effects of FAG on base layer properties using mechanistic laboratory evaluation and its practicability in pavement base layers. The investigated properties are flexural strength (FS), unconfined compressive strength (UCS), shrinkage, and resilient modulus (RM), as well as indirect tensile strength (ITS). The findings showed that the mechanical properties of the mixture enhanced when FAG was added to 80–85% of crushed aggregate, with the UCS being shown to be a crucial quality parameter. The effectiveness of FAG base material can have an impact on the flexible pavements’ overall performance since the base course stiffness directly depends on the base material properties. As a stabilizing agent for flexible pavement applications, the FAG-stabilized base appeared promising, predicated on test outcomes.
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