Red phosphor is widely used in enhancing white light emitting diodes. Recent trends show there are several efforts in improving the efficiency of lighting particularly using Europium (III) as activators in Gadolinium tungstate phosphors. In this work, LiEu(0.50-x)Gd0.50(WO4)2Smx red phosphor was synthesized using solid-state reaction. The crystal structure, morphology and photoluminescence properties of the sample were analysed. The structure of the phosphor was found to be tetragonal with space group I41/a by characterizing the phosphor using the X-ray powder diffraction (XRPD) application. The morphologies present the angular-shaped particles. The highest emission peak occurred at 615 nm corresponding to the 5D0→7F2 transition under near-UV region. The optimum amount of Sm3+ that enhanced the intensity of the host lattice at x = 0.15 mol. The improvement on the photoluminescence properties of these phosphors without any changes on the structure and crystal symmetry shows a good potential of the red emitting phosphor to be used in the light emitting diodes (WLEDs) applications.