A modern application of composite hollow fibre membrane derived from hydroxyapatite cow bone and kaolin has been developed in wastewater treatment. The common fabrication method, a process that combined both phase inversion and sintering technique was used to fabricate the membranes. The hollow fibers membrane were developed using the spinning process by using a dope that have ratio of 20:20 (kaolin:cow bone hydroxyapatite). The sintering temperature that used in this study are 1000 ℃, 1100 ℃, 1200 ℃ and 1300 ℃. The effect of sintering temperature on hollow fiber membranes were characterized by scanning electron microscopy (SEM), 3-point bending and pure water flux. The results showed that the hollow fibre membrane sintered at 1200 ℃ showed a unique membrane’s morphology, the highest mechanical strength (13.33 Mpa) and a stable pure water flux (140.6 L/m2h).