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  5. Alloyed CeCaš‘„Fe₁-š‘„Oā‚ƒ-Ī“: a calcium doped cerium iron oxide nanomaterial for photo-fenton degradation
 
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Alloyed CeCaš‘„Fe₁-š‘„Oā‚ƒ-Ī“: a calcium doped cerium iron oxide nanomaterial for photo-fenton degradation

Journal
Journal of Crystal Growth
ISSN
0022-0248
Date Issued
2025-07
Author(s)
A. Ashwini
S.D.N.B Vaishnav College for Women (Autonomous) Affiliated to University of Madras, India
G. Kaladevi
SRM Institute of Science and Technology, Ramapuram Campus, India
Mary George
Stella Maris College (Autonomous) Affiliated to University of Madras, India
Subash Chandra Bose Gopinath
Universiti Malaysia Perlis
DOI
10.1016/j.jcrysgro.2025.128177
Handle (URI)
https://www.sciencedirect.com/science/article/pii/S0022024825001253
https://hdl.handle.net/20.500.14170/16001
Abstract
The widespread application of mixed metal iron oxide materials in diverse environmental contexts makes them highly significant in heterogeneous catalysis. This study focuses on the synthesis of CeCaš‘„Fe1-š‘„Oā‚ƒ-Ī“ (x = 0, 0.2, 0.5, 0.8, and 1) nanomaterials using the sol–gel method and explores their structural, electrical, magnetic, optical, and photocatalytic properties. Comprehensive characterization was performed using Powder X-ray Diffraction (PXRD), Fourier Transform Infrared Spectroscopy (FTIR), High-Resolution Transmission Electron Microscopy (HRTEM), Brunauer–Emmett–Teller (BET) surface area analysis, Vibrating Sample Magnetometry (VSM), and UV–Visible Diffuse Reflectance Spectroscopy (UV-DRS). The diffraction peaks confirmed the formation of CeFeOā‚ƒ-based structures. The magnetic behavior of the materials was analyzed through saturation magnetization, remanent magnetization, and coercivity. The optical properties, particularly in the visible region, motivated further exploration of the photo-Fenton activity of these nanomaterials, highlighting their potential in environmental remediation applications.
Subjects
  • Heterogeneous catalys...

  • Mixed metal oxide

  • Photo-Fenton

  • Photocatalysis

  • Sol-gel

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