Now showing 1 - 4 of 4
  • Publication
    Facial synthesis of colloidal stable magnetic nanoparticles coated with high hydrophilic negative charged poly(4-styrenesulfonic acid co-maleic acid) sodium for water remediation
    ( 2023-04-01)
    Lim C.C.
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    ; ; ; ;
    Nasib A.M.
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    Wicaksono S.T.
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    Pramata A.D.
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    Zullaikah S.
    The enhancement of the colloidal stability of magnetite nanoparticles (MNPs) for environmental-related fields has greatly attracted researchers' attention. This study used a high hydrophilic negatively charged polyelectrolyte, poly(4-styrenesulfonic acid co-maleic acid) sodium (PSAAS), to enhance the colloidal stability of MNPs. Coating of the naked MNPs with PSAAS polyelectrolyte is a simple and rapid method to obtain colloidally stable MNPs while sustaining the chemical reactivity of MNPs in water purification. The prepared PSAAS-coated MNPs were characterized by scanning electron microscope, energy dispersive X-ray, Fourier transform infrared, zeta potential analysis, transmission electron microscope and X-ray diffraction. Moreover, the colloidal stability and adsorption performance tests of these naked MNPs and PSAAS-coated MNPs (with different concentrations of PSAAS coated) were investigated and compared. PSAAS-coated MNPs with 0.001 g/ml PSAAS coating possessed the best colloidal stability and the highest methylene blue (MB) dye removal efficiency (94.53 ± 0.69%). The adsorption isotherm and kinetic studies for the adsorption of MB onto PSAAS-coated MNPs were well-described by the Langmuir model and pseudo-second-order kinetic model. These magnetic adsorbents, with high separation efficiency, simple and low production cost and recyclable property, are promising as practicable adsorbents in water treatment.
  • Publication
    Effect of zinc addition on the performance of aluminium alloy sacrificial anode for marine application
    In this work, the effect of zinc addition on the performance of aluminum-based sacrificial anode in seawater was investigated. The parameters used in assessing the performance of the cast anodes are anodic efficiency, protection efficiency and polarized potential. The content of zinc in the anodes was varied after die casting. The alloys produced were tested as sacrificial anode for the protection of mild steel for marine application at room temperature. Factors such as reactivity of zinc particles in the seawater, corrosion activity during the period of experiment, pH of seawater and the electronegativity potential of zinc were collected for analysis. Overall findings shows addition of zinc increases rate of corrosion to the sacrificial anode and the protection offered by the sacrificial anodes measured and collected in PIT shows the seawater react to sacrificial anode and no porosity reaction between the anodes. The microstructure showed the intermetallic structures of β-phase which breakdown the alumina passive film, thus enhancing the anode efficiency.
  • Publication
    Parameters adjustments for facile synthesis of high magnetization iron oxide nanoparticles from natural sand
    ( 2024-02-01)
    Wahfiudin A.
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    Pramata A.D.
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    Wicaksono S.T.
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    ; ; ; ;
    This study explores the synthesis of Superparamagnetic Iron Oxide Nanoparticles (SPIONs) by leveraging natural iron sand and steel wool as primary raw materials within the co-precipitation method, which reduces the cost of production compared to the commercial counterparts. The research systematically investigated the influence of the diethylamine percentage, annealing time and annealing temperature on the SPIONs’ synthesis from natural iron sand by the co-precipitation method. Fe3O4 with varying crystallite sizes, ranging from 11.5 to 14.7 nm, were confirmed. SEM highlighted the nanoparticle agglomeration, a concern addressable through surface modification techniques, as further emphasized by TEM, which confirmed the nano-scale dimensions. Magnetic saturation values were confirmed by VSM, ranging from 37 to 51 emu/g. These values established the superparamagnetic behavior, rendering the nanoparticles suitable for versatile applications. The study identifies a potential threshold effect of the diethylamine concentration on the magnetic saturation and suggests an optimum annealing temperature for energy efficiency. This research contributes valuable insights into harnessing natural iron sand for SPION synthesis, advancing cost-effective and sustainable approaches in nanomaterial development, while emphasizing the importance of parameter customization for producing high-quality SPIONs.
  • Publication
    The effect of torrefaction reaction temperature on the Elaeis Guineensis Empty Fruit Bunch (EFB) pellet durability and calorific value
    Empty Fruit Bunch (EFB) are not being fully utilized for energy production due to its high moisture content, low density, having bulky characteristics and low calorific value. In order to improve characteristic of Elaeis Guineensis empty fruit bunch as fuel, pre-treatment process is necessary to overcome these shortcomings. Therefore, the aim of this research is to examine the effect of torrefaction reaction temperature on the Elaeis Guineensis pellet energy characteristics. The observed pellet qualities include the pellet durability and calorific value of the pellet. The torrefaction of empty fruit bunch was conducted in a fixed-bed reactor at 200 C, 220 C, 240 C and 260 C. The torrefied sample was pelletized, analysed and tested to examine the characteristics of empty fruit bunch biomass as fuel. The pelletization process was carried out by using the cold single press pelletizer and using cassava starch as binder. At higher torrefaction temperature, the decomposition of cellulose and lignin become more prominent. At the torrefaction temperature 260 C, the gross calorific value is the highest due to the removal of moisture, release of volatile matter and the decomposition of biomass components such as hemicellulose, cellulose and lignin which resulted in energy densification. By comparing the torrefied empty fruit bunch at 260 C with the untorrefied empty fruit bunch, it was found that the torrefaction increased the energy densification and pellet qualities of empty fruit bunch that can be utilized as biomass energy sources in renewable energy.