Nor Munirah Rohaizad
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Preferred name
Nor Munirah Rohaizad
Official Name
Nor Munirah, Rohaizad
Alternative Name
Rohaizad, Nor Munirah
Rohaizad, N. M.
Munirah, N. R.
Main Affiliation
Scopus Author ID
55993065000
Researcher ID
DWL-9108-2022

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Effect of carbonized coconut shell as a filler on tensile properties and water absorptivity of HDPE composite

2023 , Loh Shao Tee , Nor Munirah Rohaizad , Nor Aida Yusoff , Khairunissa Syairah Ahmad Sohaimi , Noor Ainee Zainol

Generation of agricultural wastes have detrimental effect to our surrounding especially visual impacts and inefficient land use. Some of these wastes are natural fibers which can be used as potential filler in composite materials. In this study, carbonized coconut shell (CCS) had been utilized as filler and it was incorporated in the high density polyethylene (HDPE) matrix to develop carbonized coconut shell filled HDPE composites. Firstly, the coconut shell powder was treated by sodium hydroxide (NaOH) with the concentration of 1, 3, 5 and 7 wt% for 2 hours. The 7 wt% treated coconut shell revealed better filler properties in the proximate analysis. Next, it was converted into carbonized coconut shell via carbonization process at 600 °C and used as filler in HDPE composites. The carbonized coconut shell filled HDPE composites with different filler loading of 5 to 20 wt% were prepared using extruder at operating conditions of 180 °C at 70 rpm of screw speed. The increase in the filler loading enhanced the tensile strength and the Young’s modulus of the filled HDPE composite. However, the elongation at break of the composite was observed to decrease with an increasing in the filler loading. There are some voids observed in the HDPE/CCS5 composites while good surface adhesion was presented in HDPE/CCS15 composites. The water uptake by the composites was observed to be increased with the filler loading. In conclusion, the optimum filler loading for carbonized coconut shell filled HDPE composites was determined as 15 wt% because it imparts high tensile strength with moderate water absorption properties.

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OPTIMIZATION OF DIFFERENT PARAMETERS IN THE SYNTHESIS OF BISPHENOL A IMPRINTED POLYMER VIA PRECIPITATION POLYMERIZATION FOR BISPHENOL A ADSORPTION

2021-12-01 , Nee T.N. , Noorhidayah Ishak , Azalina Mohamed Nasir , Nur Zatul 'Iffah Zakaria , Nor Munirah Rohaizad

Molecularly imprinted polymer (MIP) is used to synthesize receptors and is highly recognized against target molecules. The purpose of the study is to prepare bisphenol A (BPA) imprinted polymer that can be used to adsorb BPA molecules. The MIP was prepared by precipitation polymerization using BPA as a template, methacrylic acid (MAA) as a functional monomer, ethylene glycol dimethacrylate (EGDMA) as a crosslinker, acetonitrile as a solvent, and 1,1'-azobis(cyclohexanecarbonitrile) (AIBN) as an initiator by heating in an oil bath at 60 °C for 20 hours. The influence of several parameters (i.e., the ratio of monomer-template, the amount of crosslinker, and the amount of solvent) on the recognition capability of BPA MIP was investigated using response surface methodology (RSM). The optimal conditions of BPA synthesis are 3 mmol of monomer, 30 mmol of crosslinker, and 35 mL of solvent, which achieved an adsorption capacity of 78.111 mg/g. The MIP and non-imprinted polymer (NIP) were characterized using Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The MIP shows higher selectivity towards BPA compared to other analogs. In conclusion, the particles of imprinted polymer have a great potential in the adsorption of BPA.

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Effectiveness of banana pith as plant based coagulant for river water treatment

2023 , Noor Ainee Zainol , Tan Li Ting , Nor Aida Yusoff , Nor Munirah Rohaizad , Khairunissa Syairah Ahmad Sohaimi

River water pollution is one of the remarkable global issues that cause water crisis worldwide. Coagulation-flocculation treatment is extensively applicable for treating river water. Nonetheless, many developing countries still paying high cost for importing chemical-based coagulant as water treatment agent which is non-environmentally friendly and possess potential hazard to human health. Thus, in this research, banana pith was selected as natural coagulant as alternative material for existing chemical coagulant in river water treatment. Optimum dosage and pH of banana pith in river water treatment was examined through a series of Jar Test experiment. A comparative study on river water treatment from two different sampling sites using banana pith was evaluated in term of the percentage of turbidity and COD removal. The results indicated that the banana pith was able to effectively remove 73.53% and 92.72% of COD and turbidity respectively for Station 2 (Esplanade Pengkalan Asam) at optimum pH of 4 with desired dosage of 6 mg/L. On the contrary, banana pith eliminated 56.03% of COD and 82.80% of turbidity for river water from Station 1(Bukit Lagi) at optimum pH of 4 and dosage of 10 mg/L. Obviously, banana pith can perform well in removing turbidity and COD river water (Station 2) as compared to Station 1 for both parameters. Overall, the finding indicated that the banana pith has a potential and promising alternative natural coagulant in future for replacing commercial coagulant used in river water treatment.

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β-Glucan extraction from mycelium in spent mushroom substrate of pleurotus ostreatus and schizophyllum commune

2021-05-24 , Azalina Mohamed Nasir , Ruslan N.R.N. , Zakaria Z. , Hassan S.A.M. , Ishak N. , Nor Munirah Rohaizad , Ahmad Anas Nagoor Gunny

Spent mushroom substrate (SMS) is the biomass waste produced from the production of mushroom which generating disposal problems. To overcome the problem the extraction of bioactive compound such as β-glucan from the waste SMS could solve the problem and can also increase its added value. β-glucan appears to be promising for aiding in the cure of tumorous disease and help to reduce the cholesterol levels in blood. In this study, β-glucan was extracted and compared from two different commercial mushroom (Pleurotus ostreatus and Schizophyllum commune) from its fruiting body and mycelium on solid waste SMS using chemical extraction methods. The characteristics of physical structure, functional group and properties of extracted β-glucan was investigated. Here, Fourier-transform infrared (FTIR) and screening electron microscope (SEM) were used to identify and evaluated the structural conformations of β-glucan and physical structure. The functional properties, swelling power, viscosity and fat binding capacity were analyzed. Based on results, mycelia of Pleurotus ostreatus shown highest swelling power (11.74 g/g) and fat binding capacity (12.09 g oil/g sample) while, mycelia of Schizophyllum commune shown the highest viscosity (11.85 cP). Since the value for all functional properties shown the highest value on mycelium compare to fruiting body, thus it is strength that β-glucan extraction from mycelium solid waste has high novel properties compare with mushroom fruiting body.

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Effect of different substrates and white Oyster mushroom loading on production of fungal foam

2023 , Noorulnajwa Diyana Yaacob , Hanafi Ismail , Nor Munirah Rohaizad

In this study, agricultural wastes including rice husks, banana leaves and teak leaves were used to produce fungal foam through the cultivation with Pleurotus ostreatus fungi. The fungi are inoculated using different substrates and inoculum loadings. The mechanical properties of the foam produced were analysed. The best substrate and inoculum loading were proposed. Among the three substrates used, banana leave produced the best fungal foam in term of mechanical properties at 10 % w/w inoculum loading. The fungal foam can withstand forces high up to 30458.52 gF and have the resilience and springiness of 0.381 and 0.771, respectively. In summary, banana leave fungal foam is suitable as an alternative to the commercial Styrofoam.

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Ammonium adsorption-desorption by using rice straw biochar

2023 , Khairunissa Syairah Ahmad Sohaimi , Norhidayah Abd Aziz , Nor Aida Yusoff , Noor Ainee Zainol , Nor Munirah Rohaizad , Siti Shilatul Najwa Sharuddin

Rice straw was utilized into biochar by pyrolysis and used as adsorbent for ammonium removal. Rice straw biochar was found as one of the adsorbents for wastewater treatment. This study was conducted to analyses the capability of rice straw biochar on ammonium adsorption-desorption. Rice straw biochar was characterized by ash content, moisture content analysis, Fourier Transform Infrared (FTIR) analysis and pH of Zero Point Charge. Ash content increased meanwhile moisture content decreased as pyrolysis temperature increased. pH of Zero Point Charge for rice straw biochar was at pH 7.5. The rice straw produced at 550 °C was selected as best adsorbent for the adsorption of ammonium. The effect of process parameters such as adsorbent dosage, adsorption contact time, initial concentration and pH of ammonium were studied on the performance of ammonium adsorption. The results showed that maximum ammonium adsorption capacity was occurred at pH 7.5 by using 0.05 g of rice straw biochar in 3.0 ppm of ammonium solution for 130 minutes of contact time. Kinetic adsorption showed pseudo-second order is the best kinetic adsorption because involving a chemical adsorption as the value of R2 which was 0.9163 closer to 1. The adsorption-desorption of ammonium shown that rice straw biochar can run up to 5 cycles.

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Characteristics and properties of activated carbon from bamboo filled Styrene Butadiene Rubber (SBR) vulcanizates

2016 , Nor Munirah Rohaizad

Carbonized bamboo and bamboo activated carbon (AC) were prepared via carbonization process and chemical activation process using potassium hydroxide (KOH) as activating agent. Carbonization process was conducted at different carbonization temperature (250, 450 and 650 ºC) with heating rate of 5 and 15 ºC/min. As carbonization temperature increased, the percentage of char yield decreased, however the carbon content increased. The BET surface area of carbonized bamboo increased with increasing carbonization temperature and more pores were created as shown in SEM micrographs. Carbonized bamboo produced at 650 ºC with heating rate 15 ºC/min showed the highest potential to produce bamboo AC, subsequently used as filler in SBR compounds owing to its higher carbon content with higher BET surface area. Next, carbonized bamboo and bamboo activated carbon filled SBR (SBR-CGS and SBR-AC) compounds with varying filler loading from 10 to 50 part per hundred rubber (phr) were prepared. The effects of filler loading on the cure characteristics, physical and tensile properties were determined. Results showed that the improvement in cure characteristics for both SBR-CGS and SBR-AC vulcanizates. The physical properties of both filled SBR vulcanizates improved in terms of increment in hardness and decrement in resilience as the filler loading increased. Besides, the tensile properties for both SBR-CGS and SBRAC vulcanizates also enhanced which the tensile strength and tensile modulus as well as elongation at break (EB) increased. The morphology studies showed that both filler dispersed homogeneously in SBR compounds, resulted in good filler-rubber interaction and consequently improved the tensile properties. Comparing both filled SBR vulcanizates, it showed that SBR-AC vulcanizates have better properties than SBR-CGS vulcanizates due to the porosity of bamboo AC filler. SBR-AC vulcanizate with 50 phr of bamboo AC exhibited optimum properties and was selected to be added with transpolyoctylene (TOR) as compatibilizer. Incorporation of TOR into SBR-AC vulcanizates showed slightly increment in tensile strength and reduction in hardness and tensile modulus as the compatibilizer loading increased from 2 to 8 phr.

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Coagulation-flocculation process for turbidity removal using alum sludge from water treatment plant

2023 , J. H. Chan , Nor Aida Yusoff , Noor Ainee Zainol , Nor Munirah Rohaizad , Khairunissa Syairah Ahmad Sohaimi

The aim of this research was to utilize alum sludge, also known as water treatment residual (WTR) from water treatment plant for preparing sludge reagent product (SRP) as coagulant in removing turbidity of kaolin suspension and river water. The WTR was characterized by examine the inorganic component (functional group, and surface morphology using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscope (SEM) respectively. WTR had an amorphous structure and contained high aluminum metal constituents with 35.4 %, which can be recovered as coagulant. Acidification was conducted to recover these aluminium in WTR by using sulphuric acid and produced SRP. The optimum condition of SRP prepared from WTR was evaluated through parameters such as sludge concentration, normality and dosage of acid. It has been observed that 1 % sludge concentration acidified with 0.08 ml/ml sludge and 2.0 N H2SO4 of SRP gave the maximum percentage turbidity removal of 99.46 %. The performance of SRP in coagulation-flocculation process by using a standard jar test was studied based on the effect of pH, kaolin concentration, and SRP dosage. The highest percentage turbidity removal (99.79 %) was obtained at pH 7, kaolin concentration of 800 mg/L, and SRP dosage of 80 mg/L. The SRP performance was also compared to alum coagulant. The percentage turbidity removal of river water for both coagulants were almost similar, with 90.60 % for SRP and 91.18 % for alum respectively. Thus, SRP has the potential to replace commercial coagulant in water treatment plant in terms of costing and sustainability.

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The influences of filler loading on tensile properties and water absorption properties of carbonized sugarcane bagasse filled high density polyethylene (HDPE) composite

2020 , S S Mohammad Shah , Nor Munirah Rohaizad , Nik Noriman Zulkepli

This study synthesized carbonized sugarcane bagasse (CSB) filled high density polyethylene (HDPE) composites. The effect of pre-treatment reagent of SB with different concentration of sodium hydroxide (NaOH) was examined. The untreated, treated and carbonized SB were characterized by proximate analysis and functional group analysis. By considering all the characteristics, 7 wt% is the optimum concentration which gave lowest moisture content and highest fixed carbon (FC) content. It was chosen to undergo carbonization process at temperature of 600 °C to produce CSB and used as filler in composites. The filler with different loading was mixed with HDPE via extrusion process. The tensile properties, surface morphology and water absorption behaviour of the bio-composites were evaluated. As filler loading increased, the Young’s modulus was increasing gradually. Meanwhile, the tensile strength and elongation at break were increasing up to 5 wt% but then decreasing as filler content increased due to the formation of filler agglomeration in HDPE matrix. The deterioration of the interfacial adhesion of these composites was confirmed by the SEM observations. The percentage of water absorption is gradually increased with increasing the filler loading. In short, the optimum filler loading at 5 wt% imparts good tensile and water absorption properties of composites.

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Effects of different biomass on the properties of Pleurotus Djamor eco-friendly foam

2023 , Nur Mawaddah Majib , Sam Sung Ting , Lee Boon Beng , Noorulnajwa Diyana Yaacob , Nor Munirah Rohaizad

Plastic waste and polyurethane foam are major sources of pollution that threatens environmentsâ biodiversity. The objective of the study is to create an eco-friendly foam from Pleorotus djamor mycelium, rice husk and sugarcane bagasse. The mushroom industryâ s overabundance of materials, like oyster mushrooms and biomass, has provided an alternative method to make foam that could be beneficial for the environment. The biomass, consisting of rice husk and sugarcane bagasse, both of which are necessary for the production of foam, was evaluated as a substrate. Pleurotus djamor was inoculated on both substrates and test was done on both produced foams. Mechanical tests showed that rice husk foam had higher hardness and less springy than sugarcane bagasse foam. The morphology of both foams was analyzed using a scanning electron microscope (SEM), and the results show that sugarcane bagasse foam is denser than rice husk foam.

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