Now showing 1 - 10 of 13
  • Publication
    Tensile and morphology properties of polylactic acid/ treated typha latifolia composites
    ( 2013) ; ; ; ;
    Salmah Husseinsyah
    ;
    Muhammad Rafi’ Yahya
    This paper is focused to investigate the effect of treated natural fiber (typha latifolia) content on tensile and morphology properties of polylactic acid (PLA)/treated typha latifolia (T-TyLa) composites. The composite was compounded using heated two roll mill and the composite samples were prepared through compression molding. Tensile test and scanning electron microscopy (SEM) analysis were carried out to study the properties of PLA/T-TyLa composites. The results showed that the tensile strength of PLA/T-TyLa composites was decreased for about 43% with initial addition of T-TyLa content. The tensile modulus of the composites was increased (23%-91%) with increasing of fiber content. However, increased in fiber content reduced the elongation at break for about 53%-67% of PLA/T-TyLa composites. The optimum increment was obtained at 30 wt% of fiber content. SEM results showed that fiber dispersion was better for PLA/T-TyLa composites at lower fiber content.
  • Publication
    Morphological analysis on crosslinked plasticized starch filled with microcrystalline cellulose
    This work investigates the effect of the photo and peroxide crosslinked thermoplastic starch on the morphological properties of thermoplastic starch (TPS) / microcrystalline cellulose (MCC) films. Granulated starch will converted into thermoplastic like in the presence of glycerol as plasticizer. The amount of MCC filler carried out in this research is 0 %, 3 %, 6 %, 9 % and 12 % of the dry weight of starch. The morphological properties of photo-crosslinked TPS and peroxide crosslinked TPS were were analysed by using scanning electron microscope (SEM) and optical microscope for soil burial and weathering test. Each formulation has undergone tensile test to study their stress-strain properties and the optimum formula is obtained for subsequent studies. The increasing MCC loading increase the tensile properties of the TPS/MCC up to 6% MCC as support by morphology study. The increament in tensile strength was confirmed by the SEM study that showed better dispersion of MCC in the TPS matrix and exhibited coarser surfaces as compared to uncrosslinked counterpart. The TPS/MCC films also can last more than 20 days under soil burial test. The thermoplastic starch films will start to degrade after placed under normal weathering conditions for 20 days while the addition of rainfall will also accelerate the degradation process.
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  • Publication
    Mechanical effects on different solid to liquid ratio of geopolymer filler in epoxy resin
    Geopolymer is formed from the alkali activation of materials rich in Si and Al content with the addition of a silicate solution to enhance the properties of the materials. This paper presents research on the mechanical properties of fly ash-based geopolymer filler in epoxy resin by varying different solid to liquid ratios using sodium hydroxide and sodium silicate as the alkaline activator. However, the common problem observed from the solid to liquid ratio is the influence of curing time and compressive strength of geopolymer to have the best mechanical property. The mix design for geopolymers of solid to liquid ratio is essential in developing the geopolymer’s mechanical strength. A series of epoxy filled with fly ash-based geopolymer materials with different solid to liquid ratio, which is prepared from 0.5 to 2.5 solid to liquid ratio of alkaline activator. The tensile strength and flexural strength of the epoxy filled with fly ash-based geopolymer materials is determined using Universal Testing Machine under tensile and flexural mode. It was found that the optimum solid to liquid ratio is 2.0, with the optimum tensile and flexural strength value. However, both the tensile and flexural properties of epoxy filled with fly ash-based geopolymer suddenly decrease at a 2.5 solid to liquid ratio. The strength is increasing with the increasing solid to liquid ratio sample of geopolymer filler content.
  • Publication
    Interaction of geopolymer filler and alkali molarity concentration towards the fire properties of glass-reinforced epoxy composites fabricated using filament winding technique
    This paper aims to find out the effect of different weight percentages of geopolymer filler in glass-reinforced epoxy pipe, and which can achieve the best mechanical properties and adhesion between high calcium pozzolanic-based geopolymer matrices. Different weight percentages and molarities of epoxy hardener resin and high calcium pozzolanic-based geopolymer were injected into the glass fiber. By manually winding filaments, composite samples were produced, and they were then allowed to cure at room temperature. To determine how well the geopolymer matrices adhere to the fiber reinforcement, the microstructure of the composites’ surfaces and perpendicular sections were examined. Maximum values of compressive strength and compressive modulus were 94.64 MPa and 2373.58 MPa, respectively, for the sample with a weight percentage of filler loading of 30 wt% for an alkali concentration of 12 M. This is a relatively wide range of geopolymer weight percentage of filler loading from 10 wt% to 40 wt%, at which we can obtain high compressive properties. By referring to microstructural analysis, adhesion, and interaction of the geopolymer matrix to glass fiber, it shows that the filler is well-dispersed and embedded at the fiber glass, and it was difficult to determine the differences within the range of optimal geopolymer filler content. By determining the optimum weight percent of 30 wt% of geopolymer filler and microstructural analysis, the maximum parameter has been achieved via analysis of high calcium pozzolanic-based geopolymer filler. Fire or elevated temperature represents one of the extreme ambient conditions that any structure may be exposed to during its service life. The heat resistance or thermal analysis between glass-reinforced epoxy (GRE) pipe and glass-reinforced epoxy pipe filled with high calcium pozzolanic-based geopolymer filler was studied by investigating burning tests on the samples, which shows that the addition of high calcium pozzolanic-based geopolymer filler results in a significant reduction of the melted epoxy.
  • Publication
    Durability of inorganic fiber-reinforced alkali-activated composites
    Durability and sustainability are essential serviceability concerns for alkali-activated composites used in construction. Incorporating inorganic fibers both metal and nonmetal one in alkali-activated materials is beneficial, considering their availability, are more resistant, more rigid, have an higher melting point, and are more heat resistant than traditional fibers. The durability of natural fiber-reinforced alkali-activated composites is influenced by several factors, including type and content of fiber, dispersion and size of fiber, fiber modification, fiber moisture content, fiber alkaline degradation, and fiber mineralization. Besides, this chapter indicates the durability of inorganic fiber-reinforced alkali-activated composites in terms of crack resistance and toughness, high-temperature resistance, wet/dry cycles, freeze-thaw cycles, chemical resistance, and carbonation resistance.
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  • Publication
    Interaction of Geopolymer Filler and Alkali Molarity Concentration towards the Fire Properties of Glass-Reinforced Epoxy Composites Fabricated Using Filament Winding Technique
    This paper aims to find out the effect of different weight percentages of geopolymer filler in glass-reinforced epoxy pipe, and which can achieve the best mechanical properties and adhesion between high calcium pozzolanic-based geopolymer matrices. Different weight percentages and molarities of epoxy hardener resin and high calcium pozzolanic-based geopolymer were injected into the glass fiber. By manually winding filaments, composite samples were produced, and they were then allowed to cure at room temperature. To determine how well the geopolymer matrices adhere to the fiber reinforcement, the microstructure of the composites’ surfaces and perpendicular sections were examined. Maximum values of compressive strength and compressive modulus were 94.64 MPa and 2373.58 MPa, respectively, for the sample with a weight percentage of filler loading of 30 wt% for an alkali concentration of 12 M. This is a relatively wide range of geopolymer weight percentage of filler loading from 10 wt% to 40 wt%, at which we can obtain high compressive properties. By referring to microstructural analysis, adhesion, and interaction of the geopolymer matrix to glass fiber, it shows that the filler is well-dispersed and embedded at the fiber glass, and it was difficult to determine the differences within the range of optimal geopolymer filler content. By determining the optimum weight percent of 30 wt% of geopolymer filler and microstructural analysis, the maximum parameter has been achieved via analysis of high calcium pozzolanic-based geopolymer filler. Fire or elevated temperature represents one of the extreme ambient conditions that any structure may be exposed to during its service life. The heat resistance or thermal analysis between glass-reinforced epoxy (GRE) pipe and glass-reinforced epoxy pipe filled with high calcium pozzolanic-based geopolymer filler was studied by investigating burning tests on the samples, which shows that the addition of high calcium pozzolanic-based geopolymer filler results in a significant reduction of the melted epoxy.
      1
  • Publication
    Pengenalan pemprosesan termoplastik
    Buku Pengenalan Pemprosesan Termoplastik membicarakan beberapa asas pemprosesan dalam bidang polimer. Buku ini lebih memberikan tumpuan kepada beberapa pemprosesan termoplastik yang penting dalam bidang polimer. Objektif keseluruhan buku ini adalah untuk membolehkan pelajar mengenal pasti pemprosesan yang sering dilakukan pada bahan-bahan polimer termoplastik selain memahami konsep hubungkait di antara pemprosesan dan kesesuaian bahan-bahan polimer yang digunakan.
      16  98
  • Publication
    Effect of glycerol as plasticizer on the tensile properties of chitosan / microcrystalline cellulose films
    The chitosan/microcrystalline cellulose (MCC) film was produced through solution casting with different composition of MCC and the presence of plasticizer. This chitosan /MCC film is a biodegradable polymer due to all the ingredient was natural resources. MCC and chitosan can be found abundantly in the earth, thus, can be obtained easily. One testing was conducted which was tensile test. The optimum ratio of chitosan/MCC was 97:3 (chitosan:MCC). At this ratio, chitosan /MCC film has the highest tensile strength which was 14.73 MPa without adding any plasticizer. By the addition of plasticizer, properties of chitosan /MCC film was improved. Glycerol was used in chitosan /MCC film as plasticizer. Higher tensile strength and elongation at break follow by lower Young's modulus were the result showing that with the addition of glycerol, their film properties were able to be enhanced. About 13.57% increment in tensile strength and 47.66% in elongation at break of optimum ratio for plasticized chitosan/MCC films compared to unplasticized films.
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  • Publication
    Effects of Different Fiber Sizes in PLA/Carbon Fiber Composites on Mechanical Properties
    This study assessed the morphology and chemical composition of coir coconut husk carbon fiber, as well as the impact of fiber diameters on the physical and mechanical properties of polylactic acid composites. Researchers are studying polylactide acid, a biodegradable material. This eco-friendly material’s excellent features, generated from sustainable and renewable sources, have drawn many people. Malaysia’s high coconut fiber output made coir husk a popular commodity. Coconut fibers are lignin, cellulose, and hemicellulose. Alkaline treatment eliminates hemicellulose, oil, wax, and other contaminants from coir fibers and removes lignin. Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy were used to examine the treated coconut fibers’ chemical modification analysis and morphology. Coconut coir husk was carbonized to produce carbon fiber using a furnace operated at 300°C for 2 hours. Fiber and polylactic acid were mixed in different fiber sizes (0, 53 µm, 75 µm, and 212 µm) via extrusion and injection processing techniques. The results showed that the alkali treatment reduced the hydroxyl (-OH) group and separated the area from the carbonyl (C=O) group of coconut coir husk, which changed the filler’s hydrophilicity. The fiber size of 212 µm was discovered to have the highest tensile and flexural strength values. According to testing, the modified material structure had a better surface fill-matrix bond. Thus, generalized fiber sizing and characterization methods were developed. Regardless of the matrix, this method can characterize natural fiber strength and interfacial shear strength of varied diameters and solid contents.
      1
  • Publication
    Sifat bahan plastik
    ( 2011) ;
    Che Mohd Ruzaidi Ghazali
    ;
    ;
    Buku ini secara khusus mengutarakan dengan lengkap tentang sifat dan ciri bahan plastik melalui beberapa bab dalam buku ini dan kaedah dan prinsip pengujian serta perincirian bahan plastik. Buku ini boleh membantu pelajar dan pembaca dalam mengenalpasti perbezaan jenis-jenis bahan plastik dan memahami konsep hubung kait di antara struktur dan sifat-sifat bahan plastik.
      30  304